Issue 20, 2011
From the journal:

Chemical Communications

Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita–Baylis–Hillman reaction†‡

Sophie Dordonne,a   Benoit Crousse,a   Danièle Bonnet-Delpona  and  Julien Legros*a  

* Corresponding authors

a Laboratoire BioCIS-CNRS, Faculté de Pharmacie, Univ Paris Sud, 5 rue J.B. Clément, Châtenay-Malabry, France
E-mail: julien.legros@u-psud.fr
Fax: +33 1 46 83 57 40
Tel: +33 1 46 83 57 44

Abstract

The halogen-bonded adduct between DABCO and two molecules of perfluorooctyl iodide (DABCO·(C8F17I)2) acts as a recyclable organocatalyst for the Morita–Baylis–Hillman reaction. This “supramolecular fluorous catalyst” is readily accessible and can be recovered by simple precipitation/filtration.

Graphical abstract: Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita–Baylis–Hillman reaction

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Article information

DOI
https://doi.org/10.1039/C1CC10869G
Article type
Communication
Submitted
14 Feb 2011
Accepted
28 Mar 2011
First published
15 Apr 2011

Chem. Commun., 2011,47, 5855-5857

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Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita–Baylis–Hillman reaction

S. Dordonne, B. Crousse, D. Bonnet-Delpon and J. Legros, Chem. Commun., 2011, 47, 5855 DOI: 10.1039/C1CC10869G

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