Issue 27, 2012
From the journal:

Chemical Communications

Chirality induction in metal-induced achiral polythiophene aggregates assisted by optically active amines and polythiophene†‡

Hidetoshi Goto,§a   Yuko Yokochia  and  Eiji Yashima*a  

* Corresponding authors

a Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa-ku, Japan
E-mail: yashima@apchem.nagoya-u.ac.jp
Fax: +81-52-789-3185

Abstract

A regioregular achiral polythiophene bearing oxazoline pendant groups formed a unique optically active metal-induced supramolecular aggregate upon complexation with chiral amines or in the presence of a chiral polythiophene in a good solvent for the polymers, thus showing an induced circular dichroism.

Graphical abstract: Chirality induction in metal-induced achiral polythiophene aggregates assisted by optically active amines and polythiophene

  • This article is part of the themed collection: Chirality
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Article information

DOI
https://doi.org/10.1039/C2CC17940G
Article type
Communication
Submitted
20 Dec 2011
Accepted
30 Jan 2012
First published
31 Jan 2012

Chem. Commun., 2012,48, 3291-3293

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Chirality induction in metal-induced achiral polythiophene aggregates assisted by optically active amines and polythiophene

H. Goto, Y. Yokochi and E. Yashima, Chem. Commun., 2012, 48, 3291 DOI: 10.1039/C2CC17940G

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