Pejman
Hadi
a,
Chao
Ning
a,
James D.
Kubicki
b,
Karl
Mueller
cd,
Jonathan W.
Fagan
c,
Zhengtang
Luo
a,
Lutao
Weng
ae and
Gordon
McKay
*af
aChemical and Biomolecular Engineering Department, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China
bDepartment of Geological Sciences, University of Texas at El Paso, El Paso, Texas 79968, USA
cDepartment of Chemistry, The Pennsylvania State University, University Park, PA 16802, USA
dPhysical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99352, USA
eMaterials Characterization and Preparation Facility, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China
fDivision of Sustainable Development, College of Science, Engineering and Technology, Hamad Bin Khalifa University, Qatar Foundation, Doha, Qatar. E-mail: kemckayg@ust.hk; Fax: +852 23580054; Tel: +852 23588412
First published on 6th January 2016
The present work employs a facile hydroxylation technique to efficiently functionalize the surface of a waste-derived aluminosilicate for ultra-high heavy metal uptake via ion exchange. The functionalization process leads to the transformation of a nonporous hydrophobic waste material to a mesoporous hydrophilic material with a high concentration of ion exchange sites. The modification of the surface and textural characteristics of the mesoporous aluminosilicate has been thoroughly elucidated. The functionalization brings about the partial depolymerization of the aluminosilicate network and the transformation of unreactive bridging oxygens (BO) into non-bridging oxygens (NBO) as active sites as evidenced by 29Si NMR and FTIR. The positively-charged alkali metals bound to the NBO act as facile ion exchange sites. Ultra-high heavy metal uptake capacity of the functionalized material through a combination of ion exchange and physisorption mechanisms has revealed the great potential of this aluminosilicate material for treatment of heavy metal-laden wastewater in a sustainable manner for practical applications.
Aluminosilicate polymers generally consist of a continuous network of tetrahedrally-coordinated T–O linkages (where T = Si or Al) connected via bridging oxygens (BO).8,9 The number of these bridging oxygens located at the vertex of each tetrahedron describe the connectivity of these tetrahedra, where Qn (n = 0–4) denotes a tetrahedron with “n” bridging oxygens.10–13 The cleavage of these tetrahedra proceeds via the formation of non-bridging oxygens (NBO) which are favored in most applications due to their high activity and the possibility of interaction with other desired species. Therefore, the Q4 configuration represents the inactive unit, whereas Q3 and Q2 units, surrounded by 1 and 2 non-bridging oxygens, respectively, represent the active entities (T–OH and T–O−) within an aluminosilicate.14–16
One of the useful characteristics of these inorganic polymers is the existence of exchangeable metals (more specifically Na+ or Ca2+) in their network structure.17 These alkali or alkaline earth metals, bound to the AlO4− tetrahedra in the aluminosilicate framework, function as charge compensators.18–20 According to Bouyer et al.21 it is plausible to change the role of these metal ions from charge-balancing species to network modifiers by the hydrolysis of T–O–T′ linkages (where T, T′ = Si and Al). This hydrolysis reaction takes place by the disruption of the bridging oxygen in T–O–T′ tetrahedral unit, generating T–OH and T–O− bonds, depending on stoichiometry or reaction conditions. Because of the opening of the tetrahedral network, the charge-carrying cation can migrate from the framework to the surface and can be replaced by heavy metals if the appropriate conditions are met. Such exchange is augmented if the hydrolyzed materials have an increased surface area (i.e. higher porosity) than the parent material. The resultant aluminosilicate materials that exhibit high ion-exchange capability can have widespread applications in catalysis and wastewater treatment.22
Hydrolysis of siloxane species in aluminosilicate materials has been the subject of many investigations. Many researchers have proposed the depolymerization model of T–O–T′ in the presence of water in aluminosilicate glasses. Nevertheless, Kohn et al.23 have debated this hydrolysis model and have fundamentally ruled out the formation of terminal T–OH groups by the cleavage of T–O–T′ clusters via hydrolysis reactions. Alternatively, they have proposed the formation of protonated bridging oxygen groups (T–O(H)–T′) when the aluminosilicate comes in contact with water.24 It should be noted that there is no universal hydrolytic model that demonstrates the correct set of intermediates and products for all types of hydrolysis and all types of aluminosilicates.25,26 Although hydrolysis reactions, controversially transforming Q4 to Q3 configuration, are central in geochemistry and the glass industry, it cannot be a reliable technique to functionalize the aluminosilicate for ion exchange-based applications that require a large number and homogeneous distribution of terminal active sites (e.g. catalysis and adsorption) considering the trace amount of functional moieties developed via this technique.22
Hydroxylation is an alternative technique that can markedly increase the density of NBOs in aluminosilicates via the transformation of Q4 to Q3 units and, concomitantly, change the position of the alkali metals from charge-balancing species to network modifiers as discussed.27 In an alkaline medium, the T–O–T′ linkages undergo hydroxylation forming T–OH and T–O− species, locally charge-balanced by the cation of the alkaline medium (M), as depicted in reaction (R1).
T–O–T′+M–OH → T–OH+T′–O−M+ | (R1) |
Ion exchange capability for aluminosilicates is a direct function of the metal ions in the position of network modifiers and thus the concentration of NBO sites in the aluminosilicate structure.28 Hence, the aim of this study is to investigate the partial heterolytic cleavage of the T–O–T′ linkages of a waste-derived calcium aluminosilicate material subjected to hydroxylation reactions for enhanced heavy metal deposition via ion exchange. Further, the investigation utilizes nuclear magnetic resonance (NMR) spectroscopy, Fourier-transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS) to determine the changes in the structure of the materials. Moreover, the specific surface areas of the modified aluminosilicate materials, indicative of the tetrahedral unit opening, have been evaluated, because all these properties (i.e. specific surface area, concentration of the NBO and density of the alkali metal ions) are interlinked. Notably, it will be advantageous, in future studies, to study the structural alterations of a homogeneous aluminosilicate synthesized in more controlled conditions to shed light on the functionalization process.
For solid-state 29Si magic angle spinning (MAS)-NMR spectroscopy, NMF and A-NMF samples were packed into 5 mm zirconium oxide rotors. Direct polarization (DP-) and cross polarization magic angle-spinning (CP) MAS 29Si NMR spectra were obtained at ambient temperature using an NMR spectrometer comprising a Tecmag Apollo console and a wide-bore superconducting NMR magnet with a static field strength of 9.4 T. Spectrometer frequencies of 399.999 MHz and 79.466 MHz were utilized for 1H and 29Si irradiation. The MAS rates were 10 kHz and 7 kHz for the DP- and CP-MAS experiments, respectively. Acquisitions for the DP experiments were accomplished with a standard DP sequence using a 7 μs 29Si 90° pulse and a 60 s recycle delay for 1k transients. The CP experiments were accomplished with a standard CP sequence using a 7 μs 1H 90° pulse, a 4 ms contact pulse, and a 6 s recycle delay for 2k transients. 29Si chemical shifts are reported relative to tetramethylsilane [(CH3)4Si] by assignment of the central silane in tetrakis(trimethylsilyl)silane [(CH3Si)4Si] at −135.5 ppm as an external secondary standard.
FTIR spectra of the parent and hydroxylated materials in the frequency region 4000–400 cm−1 are presented in Fig. 3(a). The band within the range of 3800–3000 cm−1 is associated with the stretching vibrations of the hydroxyl groups in Si–OH species31 and has a very low intensity for the parent material (NMF). This result is consistent with the abundance of Q4 species compared with the Q3 units in this fully polymerized material and thus its unreactive surface properties.
The FTIR spectrum of the functionalized material (A-NMF), on the other hand, suggests that hydroxylation can considerably alter the properties of the NMF. Significantly higher intensity of the O–H stretching band for A-NMF compared with NMF reflects the favorable depolymerization of the aluminosilicate material and wide-scale transformation of Q4 species into Q3 and Q2 units. The deconvolution of the doublet band using Gaussian peak-fitting at 3471 cm−1 for A-NMF, illustrated in Fig. 3(b), yields two distinct peaks at 3525 cm−1 and 3380 cm−1 that can be ascribed to the stretching vibrations of the H-bonded vicinal hydroxyl groups32 and absorbed water molecules33 on the aluminosilicate surface, respectively. The presence of water molecules can be further confirmed by the presence of a bending vibration band at 1630 cm−1.33,34 The envelope at a frequency range of 1200–800 cm−1 is associated with the T–O linkages attached to either bridging or non-bridging oxygens.35 The deconvolution of this peak allows distinguishing between the bridging T–O–T′ and non-bridging T–O bonds. As depicted in Fig. 3(c), the sharp peak at 999 cm−1 represents the non-bridging T–O species, whereas the Gaussian component at 1097 cm−1, originally appearing as an inflection point, represents the T–O units attached to the bridging oxygens (T–O–T′). Considering the higher relative intensities of the peak attributed to the non-bridging T–O groups in A-NMF, transformation of Q4 → Q3, Q2 clusters can be confirmed.
During functionalization, the reaction of the T–O–T′ bridges with the activating agent, KOH, leads to the heterolytic cleavage of the bridging oxygen into two non-bridging oxygens, T–O− and T–OH.22 The potassium ion compensates for the charge deficiency of the former bond to form T–O−K+ (it is notable that according to the concept of the optical basicity of oxide ions proposed by Duffy and Ingram,36 the formation of Al–O−K+ is unfavorable). Also, some calcium ions, originally present as charge compensators of AlO4− units incapable of ion exchanging with other metals, can delocalize from the framework to the surface charge-deficient functional groups. Consequently, the role of some Ca2+ ions may change to network modifier although a major fraction of the calcium ions still prevail as charge balancing species AlO4− in the framework and cannot participate in any reaction. Hence, the calcium and potassium ions doped on the aluminosilicate material can act as bifunctional ion exchangers that can be replaced with more electronegative metal ions, such as heavy metals.
XPS, as another powerful technique to distinguish between the chemical states of the surface elements, has been conducted on the parent and functionalized materials. The low-resolution spectra for these two materials have been presented in Fig. 4. As depicted in this figure, the functionalization brings about significant alterations that are reflected in changes in the XPS spectrum for the functionalized material compared to the spectrum from the parent material. The intensities of the bands at 533.2 eV and 103.0 eV, ascribed to O 1s and Si 2p orbitals, respectively, have been drastically increased upon hydroxylation. This is related to the fact that hydroxylation depolymerizes the aluminosilicate structure by cleaving the tetrahedral cages of the network.
Furthermore, the band at 345 eV, associated with the Ca 2p, has also been intensified during the functionalization. This could be due to higher concentration of the Ca2+ on the surface of the functionalized material compared with the parent material. The existence of potassium atoms is demonstrated by the appearance of a distinct new peak in the binding energy of 293 eV. The disappearance of the band at 285 eV suggests that the carbonaceous components have been either volatilized as a result of relatively high modification temperature or dissolved in the KOH solution upon functionalization.
The textural properties of the parent and modified materials (see Table S2†) are also dramatically different. The parent material has a specific surface area of less than 1 m2 g−1, whereas functionalization significantly increases the surface area and total pore volume to 383 m2 g−1 and 0.85 cm3 g−1, respectively. The isotherm curves for the precursor and the functionalized material are displayed in Fig. S3.†
Several researchers have demonstrated that, assuming a tetrahedral structure for Al3+ in aluminosilicates and assuming no formation of Al–O–Al linkages in the light of a low energetic stability as a result of a strong repulsion between the negative charges on the AlO4− species (Lowenstein's rule37), NBO species will form if the molar ratio of Al/R < 1, where R is a monovalent alkali metal.38 In the case of a divalent metal, such as Ca2+, this ratio must be doubled as one divalent ion can maintain the local charge neutrality of two tetrahedral structures. The X-ray fluorescence (XRF) results (tabulated in Table S1†) indicate an Al/Ca ratio of 0.4 which is lower than the theoretical value of 2 proposed by Smets and Lommen,28 implying the presence of NBO atoms and also validating the dual-role of Ca2+ as network modifier and charge compensator of AlO4− tetrahedra.
According to Brückner et al.39 the analysis of the O peak will provide further information about the type of the BOs and NBOs that are present. The deconvolution of the O peaks for the parent and functionalized materials, illustrated in the inset of Fig. 4, is fit well by two distinct peaks. The peaks at the higher and lower binding energies represent the BO and NBO, respectively, with a chemical shift of around 1 eV between the BO and NBO (ΔEBO–NBO ≅ 1 eV). The ratio of the areas under the BO (ABO) and NBO (ANBO) peaks to the total O peak (Atot) will reveal their relative concentrations. For the parent material, BOs constitute the major fraction of the O atoms , whereas the functionalization brings about the formation of higher quantities of NBOs by the cleavage of the T–O–T′ bridges into T–O–NBO functional moieties. These T–O–NBO functional groups can react more readily with other components rather than the unreactive T–O–T′ groups and thus, further explains the higher reactivity of the functionalized material (A-NMF) compared with the parent one (NMF). It can also be argued that the peak at 531.6 eV for the NMF can be partly or wholly ascribed to the O atoms of the carbonate present in the parent material. Even if this hypothesis is valid, it will further decrease the concentration of the NBO species and thus the relative amount of BOs to NBOs will further increase in NMF. Nonetheless, this hypothesis does not apply for A-NMF, because almost all the carbon has been removed during the functionalization process (see Table S1†) and thus no carbonate peaks are expected to be present for the A-NMF in the XPS spectrum.
The shift in the binding energies of the O core electrons in the NMF and A-NMF is associated with the difference in the electron density on the O atoms by increasing the NBOs.38 According to Alexander et al.40 the bond between the charge compensators and BOs is more ionic than that of the network modifiers and NBOs. Therefore, charge compensators will decrease the electron density on the O atoms and hence the binding energy will be higher when most of the Ca2+ act as charge compensator, as in the case of NMF. As the amount of NBO components increases, the degree of the ionicity of the calcium ions decreases, resulting in higher electron density on the O and lower binding energies. Similar behavior has already been reported for borosilicate glasses,41 where higher concentration of NBO components results in lower binding energies.
NMR results confirm the condensed structure of the NMF. As illustrated in Fig. 5(a), 29Si DP spectrum from NMF shows a broad peak with a maximum at a chemical shift of −99.4 ppm. This peak is clearly related to an aluminosilicate with a range tetrahedral Si sites.42 The sample has a Si/Al ratio of approximately 5 and therefore one would expect a maximum around the shifts of species such as Q4[1Al]. However, there is a distribution of additional Q4[nAl] sites with n = 0–4 that should be present, as well as some sites with non-bridging oxygens (but without hydroxylation, as no signal can be observed in the 1H–29Si CP spectrum of this sample). The lack of a CP signal indicates the absence of detectable numbers of hydroxyl groups using the CP method, but does not rule out the presence of some surface bound hydroxyls on this low surface area sample. These NMR results, together with very low surface area of the sample, agree with the predominance of Q4 structures within the aluminosilicate.
In the case of the functionalized aluminosilicate, the major peak in the 29Si DP spectrum is observed at −82 ppm. If we ascribe at least a portion of this peak to arise from non-Q4 species with 1 or 2 Al next-nearest neighbors (NNN) to move the resonance to lower chemical shifts, a peak at the same chemical shift (around −82 ppm) should also exist in the 29Si CP spectrum. This is confirmed in Fig. 5(b). The additional spectral intensity with 29Si chemical shift values observed closer to 0 ppm is believed to be caused by some modified T-groups, i.e. direct bonding of some of the C with the aluminosilicate network, with additional presence of Al or metal cations in the NNN coordination sphere. The CP spectrum agrees with this observation, as no peak exists near −30 to −50 ppm. The peak at −66 ppm can be either some T groups associated with –OH or other Q groups (Q3, Q2) with multiple Al or NBOs nearby.
Material | Maximum metal deposition (mmol g−1) | Ref. | |||||
---|---|---|---|---|---|---|---|
Cu2+ | Pb2+ | Zn2+ | Co2+ | Ni2+ | Cd2+ | ||
a Metal depositions lower than 0.2 mmol g−1 for all the metals have not been included in the table. b The metal deposition capacities of A-NMF is on a wet basis with a moisture content of approximately 20 wt%. The capacities on a dry basis will be higher than the tabulated amounts. | |||||||
NMF | <0.1 | <0.1 | <0.1 | <0.1 | <0.1 | <0.1 | This work |
A-NMFb | 2.82 | 3.21 | 2.00 | 3.12 | 3.11 | 2.05 | This work |
Zeolite and silicate heavy metal uptake capacities | |||||||
Zeolite | 0.44 | 0.21 | 43 | ||||
Zeolite 4A | 0.84 | 0.48 | 0.19 | 0.13 | 44 | ||
Clinoptilolite | 0.4 | 0.13 | 0.26 | 0.04 | 45 | ||
Zeolite-activated carbon composite | 1.72 | 2.65 | 1.20 | 1.44 | 46 | ||
Na–X zeolite | 1.16 | 1.68 | 47 | ||||
Cancrinite zeolite | 2.08 | 2.13 | 1.15 | 1.24 | 1.53 | 48 | |
Modified zeolite | 1.43 | 2.03 | 0.87 | 49 | |||
Fly ash zeolite | 1.30 | 0.72 | 50 | ||||
Functionalized silica | 0.60 | 0.20 | 0.20 | 0.25 | 51 | ||
Amine-functionalized silica | 0.83 | 52 | |||||
Modified SBA-15 | 0.92 | 0.4 | 0.32 | 0.36 | 53 | ||
Silica nano-hollow sphere | 0.47 | 0.53 | 0.36 | 54 | |||
Thiol-functionalized silica | 0.44 | 55 | |||||
Commercial ion exchanger heavy metal uptake capacities | |||||||
Dowex 50W | 0.35 | 0.23 | 0.30 | 0.12 | 0.25 | 71 | |
Amberlite IR-120 | 0.34 | 0.41 | 1.3 | 0.82 | 0.90 | 72 | |
Amberlite IRC-748 | 1.13 | 1.06 | 73 | ||||
Lewatit CNP 80 | 0.16 | 0.35 | 0.31 | 0.32 | 0.04 | 74 | |
Lewatit TP207 | 1.98 | 1.78 | 1.63 | 1.97 | 1.78 | 75,76 | |
Amberjet 1500H | 0.39 | 77 | |||||
Ambersep 252H | 0.18 | 77 | |||||
Suqing D401 | 2.00 | 1.88 | 1.70 | 2.10 | 1.88 | 75,76 | |
MCM-41 | 0.71 | 0.68 | 0.41 | 0.71 | 0.67 | 75,76 |
The ion exchange mechanism of the heavy metal uptake onto the functionalized material is verified by the liberation of K+ and Ca2+ into the medium as the heavy metal ions are deposited on the aluminosilicate. Fig. 6 illustrates the liberation of the K+ and Ca2+ into the solution by Cd2+ deposition. As higher amounts of Cd2+ are deposited onto the hydroxylated aluminosilicate, higher concentrations of K+ and Ca2+ are liberated into the medium. Considering that each heavy metal ion, M2+, can be exchanged with either one Ca2+ or two K+, the theoretical mass balance between the liberated and deposited metals does not thoroughly conform with the experimental findings. In other words, more heavy metal ions are being deposited than the liberated alkali metals. Electroneutrality may be maintained by the incongruent dissolution and leaching of Al3+, verified by the liberation of Al3+ species into the heavy metal containing solution.56 This reveals that although the major mechanism of the heavy metal uptake proceeds via the ion exchange with the lighter metal ions, some heavy metal ions can also be deposited via other routes. This route has been later elucidated to be electrostatic interaction between the heavy metal ions and the lone pair of electrons on the BO.
The mechanism of heavy metal uptake on the functionalized material is further elucidated by additional analytical methods. As depicted in Fig. 7, deposition of heavy metals on the aluminosilicate-type materials induces appreciable spectral changes in the fingerprint infrared regions of the Si–O band at ∼1300–800 cm−1.
Previous research utilizing Raman spectroscopy of silicate materials has shown that the stretching vibrations of the Si–O band envelope in the range of 1250–850 cm−1 can be fitted with four different components.57 These components have been ascribed to Si–BO species in Q4 units and three Si–NBO stretching vibrations corresponding to various numbers of NBOs (Q3 and Q2). Nevertheless, although it is mathematically feasible to acquire a proper fit for these four components, we believe that it is not plausible to confidently articulate a solid distinction between the Q3 and Q2 components of Si–NBO linkages. Instead, it is more pragmatic to deconvolute the band into two components using Gaussian functions for both Si–BO and Si–NBO species. The component at 1097 cm−1 is assigned to the tetrahedral BOs related to a Q4 configuration of T–O–T′ species of the aluminosilicate, while the component at lower frequency (999 cm−1) corresponds to the NBOs of Q3 or Q2 units.
Upon metal introduction, another component, centered at approximately 870 cm−1, appears in addition to the two components in the A-NMF. Kubicki & Toplis58 performed calculations on the effect of Ca2+ on the T–O–T′ bond length. According to their calculations, the interaction of Ca2+ with this bond will lengthen the T–O–T′ linkage, which in turn, will lower the vibrational frequency. Using an anharmonicity coefficient of 0.893, the interaction between the Ca2+ and T–O–T′ is expected to result in a peak at 922–954 cm−1. Stronger interaction of the heavy metals with the bridging oxygens will further weaken the T–O–T′ bond and result in peaks at frequencies as low as 870 cm−1. Hence, this new Gaussian component is an indication of the interaction of the heavy metals with the aluminosilicate. The type of this interaction is still open to dispute. In another study, Kubicki & Sykes have attributed the peak at 870 cm−1 to the interaction of the BOs with H+ and formation of a T–(OH)–T′ configuration, verified by molecular orbital calculations.24 Kohn et al. have also assigned the shoulder at around 888 cm−1 to the T–(OH)–T′ clusters in sodium aluminosilicate glasses.23 Accordingly, the lone pairs on the O atoms of the BO can induce dipole moment due to the large electronegativity difference between the Si and O atoms which, in turn, can cause the electrostatic interaction between the positively-charged heavy metal ions and the lone pairs.
In order to test this hypothesis, the pH changes in the medium have been closely monitored. We have observed a drastic pH increase when the A-NMF is placed into pure water. The dissociation of water molecules into H+ and OH− and the interaction of the former with the T–O–T′ linkages to form T–(OH+)–T′ could bring about the observed pH increase, because OH− species would be released into solution. Placing the A-NMF in the heavy metal-containing solution increases the aqueous pH level to a much smaller extent. This phenomenon is associated with the stronger electrostatic interaction of M2+ with the O atoms of T–O–T′ clusters rather than the protonation of the BO. In agreement with the findings of Kubicki & Sykes,24 this interaction generates a strong IR band at 870 cm−1 in the metal-doped aluminosilicate material. This hypothesis suggests the existence of an interaction between the BO and heavy metal ions in addition to the ion exchange mechanism. This interpretation accounts for slightly higher metal deposition compared with the liberated ions, as suggested earlier.
Heavy metal deposition also alters the envelope at 3800–3000 cm−1 assigned to the OH stretching vibrations of the H-bonded silanols and the water molecules. Metal uptake brings about the splitting of the band at 3460 cm−1 in A-NMF into three small peaks/shoulders/distortions in metal-doped A-NMF. These new peaks/shoulders are located at approximately-fixed positions for all the metal-doped aluminosilicate samples, appearing around 3415 cm−1, 3465 cm−1 and 3550 cm−1. These bands are attributed to hydrated metal clusters with various coordination numbers. According to O'Brien and Williams,59 partial electron transfer from the water molecules to the cations results in different hydrogen bonding strength in various conformations and thus different vibrational frequencies. Hence, the emergence of several bands in close proximity to each other after the heavy metal uptake is consistent with the hydration of the heavy metals with different coordination numbers and various hydrogen bonding abilities.
XPS can provide information on the oxidation states of the metals deposited on the aluminosilicate. These oxidation states are of high significance in the catalytic behavior of the metal-deposited aluminosilicates. The XPS results from the Cu-A-NMF sample is presented in Fig. 8 and is compared with that of the A-NMF. As depicted in Fig. S4,† there is a remarkable reduction in the peak intensities of the K+ and Ca2+ due to their ion exchange with the Cu2+. Also, the appearance of a new symmetric peak centered at 935.2 eV after the Cu2+ deposition, indicative of the Cu 3p3/2 core region, clearly indicates the incorporation of isolated cupric ions in a spinel-like structure via an ion exchange mechanism.60–62 The high-resolution spectrum of copper (inset of Fig. 8) displays the existence of shake-up satellite features at approximately 944 eV and 964 eV for the 3p spin orbit doublets (Cu 3p3/2 and Cu 3p1/2 core levels).63–65 These satellite peaks form by the electron transfer from a ligand orbital to the metal d orbital (np ligand → 3d copper) which indicates the open 3d9 shell configuration of bivalent copper species. This electronic structure suggests the ability of the Cu-doped aluminosilicate to perform catalytic reactions requiring electron transfer.
The deconvolution of the O peak demonstrates that the concentration of the NBO is not significantly changed by the metal uptake, where the is calculated as 0.73 and 0.72 for the A-NMF and Me-A-NMF, respectively. The constant relative concentration of the non-bridging oxygen is very critical, as it suggests that the structure of the aluminosilicate remains intact during the metal deposition and BOs do not re-form through re-combination of the NBOs. Therefore, the substitution of an alkali or alkaline earth metal with a heavy metal does not change the role of the O atoms in the network. Nonetheless, due to the intrinsic differences in the electronic environments of the light and heavy metals, apparent chemical shifts of the BO and NBO peaks to higher binding energies by the heavy metal deposition can be detected.66 When Ca2+ and K+ are replaced by more electronegative heavy metals, a partial transfer of the electronic charge from the neighboring O to the heavy metal occurs, reducing the electron density on the O atoms which thus results in an increase in the binding energy of the O core element from 530.5 eV for A-NMF to 531.6–531.9 eV for Me-A-NMF.
The TOF-SIMS depth profile, illustrated in Fig. S5,† shows the distribution of K+ and Ca2+ in the functionalized material and reveals its distribution change by deposition of heavy metals. The concentration of K+ steadily decreases as a function of depth from the surface, but the Ca2+ is approximately constant in the course of sputtering. This behavior is associated with the roles of these two metals in the functionalized material, where all K+ ions play the role of a network modifier, whereas a major fraction of Ca2+ ions acts as charge balancing cations for AlO4− clusters and only a small fraction, migrating from the bulk to the surface, have the same role as K+ ions. When heavy metal is deposited on the aluminosilicate material, the concentration of Ca2+ remains unchanged, whereas the depth profile of the heavy metal is markedly identical to that of the potassium in the functionalized material. The dependence of the heavy metal concentration in different depths to the K+ and Ca2+ concentrations further validate the ion exchange mechanism for the deposition process.
In this study, NMF is a material of unknown nature, which has been synthesized, processed, and stored with unknown level of control. In fact, NMF is an amorphous Ca-aluminosilicate, a metastable material that represents one of myriad states possible for this chemical composition. In addition, it was neither homogeneous nor pure because it is a waste-derived material. Therefore, the analysis of the NMF structure can create great controversy and be a challenge in this work. Despite the inhomogeneous structure of the NMF, whether the parent material was fully polymerized or it had a certain Q3/Q4 ratio (as suggested by the XPS results) is not the critical issue – at this level of uncertainty, NMF material can be considered as not more than just a control material to study the structural alterations during the functionalization and ion exchange. The key finding is the tendency of this material to decrease the degree of polymerization after aqueous thermo-alkaline reaction. Analytically-proven manifestation of such a decrease in the A-NMF relative to the unaltered NMF is sufficient regardless of the exact state of the starting point. The key to this study is the newly-formed NBO surface sites that improve the ion exchange performance of the parent material. It has been clearly demonstrated by XPS and NMR that this alteration occurs, and the NBO concentration is higher for the altered material.
Footnote |
† Electronic supplementary information (ESI) available. See DOI: 10.1039/c5qi00182j |
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