Abd El-Hady B. Kashyout
*a,
Amany Hassan
b,
Gasser Hassan
c,
Hassan El-Banna Fath
d,
Abd El-Wahab Kasseme,
Hisham Elshimy
f,
RanjanVepa
g and
Mohammad H. Shaheed
g
aAdvanced Technology and New Materials Research Institute, City of Scientific Research and Technological Applications (SRTA-City), Alexandria, Egypt. E-mail: akashyout@srtacity.sci.eg
bFaculty of Engineering, Alexandria University, Egypt
cInformatics Research Institute, City of Scientific Research and Technological Applications (SRTA-City), Alexandria, Egypt
dEgyptian Association for Water and Energy (EWE), Egypt
eFaculty of Agriculture, Alexandria University, Egypt
fPharos University in Alexandria, Egypt
gSchool of Engineering and Materials Science, Queen Mary University of London, Mile End Road, London E1 4NS, UK
First published on 8th April 2021
For many socio-economic and demographic issues, majority of the Egyptian population live near the Nile River for thousands of years. Shortage of freshwater resources at remote and rural areas is limiting population settlement and development. Therefore, it is necessary to find alternative solutions including saline water desalination processes to assist obtaining fresh water for domestic and industrial purposes in these remote areas. The energy needed for the desalination process represents another challenge due to the available fossil fuel limitation, increasing prices and their negative impacts on the environment. These challenges may be tackled by applying hybrid renewable energy (RE) resources such as solar and wind energies as the driving power for the desalination technologies. Many studies are conducted in Egypt, Middle East region and worldwide investigating the possibilities of different desalination systems driven by RE. This article presents a recent review of the global desalination processes with a focus on membrane desalination systems such as reverse osmosis (RO), membrane distillation (MD), hybrid desalination technologies and processes as well as advanced plasmonic nanomaterials for water distillation derived by RE suitable for remote and isolated areas. Some recent activities for coupling desalination systems with hybrid RE carried-out by the co-authors will be highlighted.
Hassan El-Banna Fath | Prof. Hassan El-Banna Fath (E-mail: h_elbanna_f@yahoo.com) is an expert in desalination and energy technologies with wide academic and industrial experience. Academically, he was a Professor in different universities in Egypt, the UAE, the KSA, Iraq, Qatar and Lebanon. He supervised many MSc and PhD students and established different desalination laboratories, e-learning institutes and centers, led many RDI including Mega Project, published “Desalination Technology” book, co-authored DESWARE, filed six patents and published over 180 papers. Industrially, he is Senior Researcher, Doosan (Koria-UAE), Head of Efficiency (SWCC), Training SAMAREC & SCECO-W (KSA), Process Engineer, AECL/OH, and now the Director, Desalination and Energy Systems (DES) (Canada). |
Globally, water demand is projected to increase by 55% in 2050, mainly due to high GDP growth rate that will increase water demand for manufacturing, power generation and domestic sector use by 400%, 140% and 130% respectively.2 About 40% of the world population will suffer from water scarcity due to these demands. Desalination is the most energy-intensive water treatment process that consumes 75.2 TW h per year, about 0.4% of global electricity and 76 million ton of carbon emission. Energy consumption during the desalination process is mainly dependent on the water sources, nature of existing contamination and the process type itself. The current energy-intensive desalination processes, with 10–15% efficiency, are not sustainable for future water supplies. For future sustainability, innovative membrane materials are proposed but they need 5–10 years of intensive research for commercial production. However, thermally driven desalination technology hybridization can achieve 20–25% of efficiency, close to sustainable production zone.
In Egypt, the increasing need for freshwater is due to the high growth rate of population in addition to the natural shortage of freshwater resources in areas that are located far from the Nile River.3 This led to high needs for the development of desalination systems that consume minimum energy, mainly depending on renewable resources. Lack of fresh water is also one of the factors causing internal immigration from Upper Egypt and small villages to big cities, causing overload on cities, unemployment and crimes. Hence, there is a big need to develop small-sized and standalone desalination plants that are suitable for rural areas, where lack of fresh water or grid electricity exists.4
Desalination systems are classified into thermal and membrane processes. The desalinated feed water may be either brackish water or sea water of different salinity ranges.5 The desalination system for each salinity has different requirements in order to produce the needed quality of the freshwater. There are different types of desalination systems that vary in initial and running costs, required equipment and the rate of freshwater produced. The energy utilized for the desalination processes may come from many sources such as conventional fossil fuels, wind mills, solar plants and electricity grids. Not all areas that need desalination have access to electricity grid on regular basis. Thus, the need for alternative energy resources is essential for direct community needs and for driving the desalination processes. The utilization of a RE source allows continuous energy supply for the desalination process.
Generally, RE desalination market is often solar energy driven (accounts for about 70% of market). High cost of grid connection for small desalination systems in remote areas limits the widespread use of them and consequently the needs of standalone RE driving systems that enable small communities utilize and benefit from desalination technology systems.
The use of solar energy systems for desalination processes can be either by direct or in-direct methods. The direct methods may include solar still systems, which could be utilized in systems with low yield of pure water but at low cost of production for the simplicity of constructed systems. However, the in-direct systems are considered as suitable options for medium-volume desalination plants.6 In in-direct methods, solar energy is transformed into electricity that is then used to drive the desalination process. Electrical storage systems in hybrid renewable energy technologies have a great effect in both the desalination performance and total water cost of the desalinated water. In general it could be found as a challengeable issue, which potentially hinders the broad application of PV/RO desalinations. Neglecting, however, challenges associated with the conversion, storage and utilization of RE resources coupled with the operation and maintenance issues thereof, with the attendant critical implications on the overall water production, would be nothing less than unthinkable.7
In the following sections, a general review of the desalination systems is given and followed by a survey of the RE-driven desalination systems. An in-depth discussion of challenges facing the use of RE in desalination is then given with emphasis on desalination systems in the MENA region and special attention will be paid to Egypt for raising hybrid RE systems driving hybrid desalination technologies. In addition, a review of desalination technologies mainly RO, MD and Integrated RO–MD systems will be discussed.
Fig. 1 Worldwide desalination processes. (a) Effective water desalination processes and technologies (adapted from ref. 9). (b) Proportion of installed desalination plants in terms of production capacity in cubic meters per year (adapted from ref. 9 and 14). |
Parameter for best-in class desalination plants | Year 2016 | 2022 | 2035 |
---|---|---|---|
Cost of water (US $ per m3) | 0.8–1.2 | 0.6–1.0 | 0.3–0.5 |
Construction cost (US $ per MLD) | 1.2–2.2 | 1.0–1.8 | 0.5–0.9 |
Electrical energy use (kW h m−3) | 3.5–4.0 | 2.8–3.2 | 2.1–2.4 |
Primary energy use (kW h m−3) | 7.45 (ref. 13) | — | — |
Membrane productivity (m3 per membrane) | 28–47 | 35–55 | 95–120 |
In the next sub-sections, a review of the desalination technologies, mainly RO, MD, integrated RO–MD and hybrid desalination systems will be presented.
Capillary Channel Plasmonic Water Desalination (CCPWD) systems have been recently developed and considered as one of the emerging technologies.16 They used many nanomaterials as evaporators. These materials include gold plasmonic nanomaterials, graphenes, carbon nanotubes, and graphene oxides. Capillary channels are constructed from carbon foams, cellulose fibers, porous NiO discs, cotton rod-polystyrene and polytetrafluoroethylene. Thin-film structures of super dark meta-surface composed of dispersing gold plasmonic nanostructures in a filter paper demonstrated a solar thermal efficiency of 87% when exposed to an intensity of only 2.3 Sun, maintaining a stable efficiency of 90% at higher solar intensities.17
Other thermal processes as MD can however operate at temperatures below the saturation conditions as will be discussed below. MD systems usually are known as a membrane separation thermal process that the vapour molecules transfer with the force of partial pressure difference across micro-porous hydrophobic membranes.17 The MD system has four well-known configurations; (i) direct contact MD (DCMD), (ii) air gap MD (AGMD), (iii) sweep gas MD (SGMD) and (iv) vacuum MD (VMD). MD processes have many advantages over RO technologies such as lower driving pressure, less fouling as well as high feasibility to combine with other processes (UF, NF or RO), creating integrated separation systems with higher performance. However, MD disadvantages include more cost-effective, higher rejection factor and relatively large membrane pore size.
The MD membrane is identified by its main characteristics, which are as follows: liquid entry pressure (wetting pressure), membrane thickness, membrane porosity and tortuosity, mean pore size and pore size distribution and thermal conductivity. The membrane used in the MD system should have low resistance to mass transfer and low thermal conductivity to prevent heat loss across the membrane material. Other factors to be considered are high thermal stability of the membrane in raised temperatures and good values for resistance to chemicals, such as acids and bases. The pore size optimum values are determined for each feed solution and operating condition. The operating parameters of the membrane are feed temperature, the concentration and solution feature, recirculation rate, air gap (in air gap MD) and membrane type.
The advantages of the MD process include lower operating pressure and operating temperatures (below the boiling point of feed solution), lower vapour space, unlimited to high osmotic pressure and very high separation factor of non-volatile solute. Potential applications for concentrating aqueous solutions or producing high-purity water can use any form of low-grade waste heat or be coupled with solar thermal energy systems, which makes it attractive for the production of potable water in arid regions.
An extensive review of the developed MD systems for desalination processes was presented by ref. 18. In this reference, a technical review and assessment of MD is presented and addresses the latest development in MD configurations, membranes, integration with other processes and the process modelling. The MD high membrane area-to-volume ratio allows it to operate at a lower temperature with respect to traditional distillation processes and exploits operational simplicity for applications in integrated membrane systems or as stand-alone small desalination units. The limitation of MD usage is due to the low water flux and reduction of long-term performance due to the wetting of the hydrophobic microporous membrane. MD membranes' cost is still of high price for the wide application distillation systems.
Gonzalez et al.19 discussed the performance of different MD membranes properties, configuration, wetting and fouling, energy consumption and water cost. As for the material, it was found that the PTFE (polytetrafluoroethylene) membranes perform better than PVDF (polyvinylidene) and PP (polypropylene) membranes. Larger scale plants are needed to illustrate the feasibility of using MD sustainable water production.
A RO desalination system is composed of four main subs-systems; pre-treatment, pumping with high pressure, membrane stacks, and post-treatment. The high-pressure pump forces the pre-treated feed water to flow through the membrane surface. Brackish water (BW) of salinity ≤20000 ppm operates with a pressure ranging from 17 to 27 bars for delivering efficient fresh water through the RO membranes. These low pressures applied in BWRO systems allow the application of low-cost plastic-made components. RO technology has many major impacts that may limit its wide application such as the environmental effects of the brine rejection and the limited recovery of product water for high-salinity feed water. Increasing the brine concentration in the RO systems limits the recovery ratio, leading to an increase in the osmotic pressure, and consequently, the energy consumption and scaling on the surface of RO membranes. This recovery ratio is between 35 and 45% for seawater and increases to 75–95% for brackish water as reported by ref. 20.
Discharging the brine concentrates to surface water causes serious effects ranging from the change of water salinity and consequently the dissolved oxygen (DO) concentration in water. This will greatly affect the organ life around the area of discharging. Mickly21 determined a salinity limit of less than 10% for surface water discharge. It could also be noted that the rejected brines may contain higher concentrations of toxic contaminants depending on the composition analysis of the brackish or seawater that will affect both human life and agriculture activities.
The increase in the recovery ratio of RO membrane causes a consequent increase in the osmotic pressure through the feed side of the RO unit. This requires an increase in the feed pressure and, therefore, the required feed flow and specific energy will decrease for the same specific product flux. The minimum required energy depends on the feed water salinity and recovery ranges between 50 and 55%.22
A review on the RO pre-treatment technologies was presented by S. Jamaly, et al.23 These technologies include two main directions; conventional one like coagulation, flocculation, and scale inhibition and the second one is non-conventional such as micro-filtration (MF), ultra-filtration (UF) and nano-filtration (NF). Operational costs of non-conventional pre-treatment systems are usually higher than the conventional one. They produce water with higher quality and the membrane capital cost increases by 20–40%. In cases of high-salinity seawater and sites with limited space, the membrane technologies (UF/NF) pre-treatment systems favoured their selection in desalination systems.
Nanofiltration (NF) membranes are utilized in pre-treatment processes for many benefits to raise the RO flux and recovery rate as well as reduce the replacement rate of RO membranes. NF also has the ability to treat surface water with poor quality and reduce cleaning and disinfection requirements for the RO membranes. This pre-treatment step of incorporation of the low-pressure NF membranes increased the life span of the high-pressure RO membranes by about 20–30%.
Other hybrid desalination processes usually constituted thermal/RO systems, combining the benefits of high separation efficiency of multistage flash (MSF) and low energy consumption of RO.26 The MSF desalination process is mainly based on the flash evaporation principle, where seawater is heated until boiling while exposing to reduced pressure. Generally, the flashing chamber receives the heated seawater by low pressure steam up to 90–120 °C. It starts to boil and evaporate with the effect of flashing.27 The remained brine passes to the next stage in another flash chamber, with the exposure to further flashing processes under low pressure, which means that water is flashed in multisequence flashing without any additional heat. For each stage, the pressure is maintained below the pressure corresponding to the saturation temperature of the stage feed. Vapour is produced and then it condensed and cooled by pre-heating the incoming seawater that reduces the cost of the MSF process with the introduction of such heat regenerative step.
The multiple effect distillation-adsorption distillation (MED-AD) hybrid desalination system was experimentally presented.28 A high increase in water production (two to three folds) had been recorded that was attributed to the synergetic operation of the conventional MED and the AD systems. The hybrid cycle was demonstrated using feed portable water and the cycle performance presented here can vary with real sweater operation. The integration between MED and AD systems prove that it is simple and involved no major moving parts. Therefore, this hybridization of the thermally driven cycles of MED-AD has demonstrated their excellent thermodynamic synergy between the thermally driven processes. A quantum improvement in the energy efficiency as well as increasing water production is expected. The advent of the MED-AD cycles is one such example where seawater desalination can be pursued and operated in cogeneration with the electricity production plants.29
A proposed system consists of a tri-hybrid desalination integration to enhance the overall recovery up to 81% instead of the present 56%.30 They supposed to leave the conditioned brine from the RO processes and supply the multi-evaporator adsorption cycle (RO + ME-AD) driven by low-temperature industrial waste heat sources or solar energy. A developed FORTRAN software was used to conduct the mathematical model of the overall system. The concentration of the rejected final brine from the tri-hybrid cycle can vary from 166 000 ppm to 222 000 ppm if the RO retentate concentration varies from 45 000 ppm to 60 000 ppm. Economic analysis of this proposed tri-hybrid cycle shows that it can achieve the highest recovery of about 81% accompanied by the lowest energy consumption of 1.76 kW helec m−3.31
The membrane-based RO method is known to be more energy efficient than the MSF/MED, and therefore, they have attained merely less than 13% of the thermodynamic limit, where the best overall specific electricity consumption (SEC) of desalination is about 3 to 5 kW helec m−3, corresponding to 6.0 to 10 kW hpe m−3 with a weighted power plant efficiency of 57%.32
Fig. 2a shows how RE resources could be integrated with different desalination technologies. These can be discussed as follows:
Fig. 2 RE-driven desalination, (a) integration of RE with desalination technologies, (b) share of globally installed water desalination technologies coupled with renewable power sources (adapted/reproduced from ref. 36 with permission from Elsevier, copyright no. 5032710255216). |
(1) RO process requires one source of energy (which is electricity).
(2) RO is a one-phase (liquid) desalination process.
(3) RO requires less specific energy consumption compared to other technologies.
(4) RO plant is made up of modules, which is easy to install, maintain, operate, and requires compact space.
(5) The driver PV/CPV modules can be installed on the roof of the RO building (i.e. PV/CPV panels will not need any additional areas).
(6) PV/CPV is modular, easy to install, with low maintenance costs.
(7) PV/CPV modules operate well in arid areas, produce direct current to drive DC motors, and are independent of the main electricity power supply.
Fig. 2b shows the world-wide use of the various desalination technologies using solar power sources.7,36 Share of globally installed water desalination technologies coupled with renewable power sources shows an accumulated desalination capacity of about 1–2% of the total water desalination with 40% contribution from RO-PV systems.
Fig. 3 shows an assembly of a typical RO desalination plant coupled with a PV generator. This configuration collects (i) a set of storage battery blocks with the system to stabilize the energy input to the RO unit and to compensate for solar radiation variations and (ii) a charge controller to protect the battery block from deep discharge and overcharge, and RO desalination system.38 The author discussed the different types of PV-RO combined systems. These systems are RO powered by a battery-less PV system, RO powered by PV connected to a displacement pump via a variable DC to DC converter and PV connected to the power grid. In the case where a PV-RO system is powered without battery,39 the desalination rate was found to increase by 5% if the feed pressure is operated under varied values depending on the PV output power.
It could be explained also when using a permeate buffer tank with varying feed pressure, the production is 36% and 28% higher than that of constant and variable pressure operation of the plant without using a buffer tank. Plant start-ups and shutdowns are determined from the signals of both low levels and high levels from the permeate tank. The overall system capability and its tank volume could be designed, so that the plant has the ability to run for several hours continuously with maximum performance. This clearly means that the less frequently the plant is shut down, the better the system performance.
Helal et al.40 explored the fully solar-driven PV–RO plant and found that the highest capital cost among three designs, US $18277 per year. In addition, it was also found that the cost of water production from the fully solar-driven PV-RO plant was 7.34 $ per m3 which is very competitive at that time with that of the diesel-assisted PV–RO plant, which was 7.21 $ per m3. It was also found that the utilization of battery-less PV with RO is more economical than diesel, but it was less economical than the use of electrical power grid.
Kaya et al.41 calculated the levelized cost of water (LCW) in Abu Dhabi desalination plant and found that PV-driven seawater RO (SWRO) desalination plant has total energy consumption of 3–4 kW h m−3 with an investment cost of 900–2500 $ m−3 d−1, which yields an LCW of 0.5–1.2 US $ per m3. The estimates are also made for PV-driven brackish water RO (BWRO) plant that has a total energy consumption of 0.5–2.5 kW h m−3 with an investment cost of 300–1200 $ m−3 d−1, which yields an LCW of 0.2–0.4 US $ per m−3. The author indicated that the desalination water cost has been dropped by about 14 times, which is directly related to the large drop in PV prices between 2008 and 2019.
A recent review discussed the consumption of energy in desalination processes, where a large amount of electricity and heat derived from fossil fuels is consumed to produce fresh water.42 They reviewed a photovoltaic thermal collector integrating desalination technologies such as solar still, humidification dehumidification, multiple effect distillation, reverse osmosis, multiple stage flash and membrane distillation. The primary focus was made on the fruitful utilization of electricity and heat from the photovoltaic thermal collector in desalination systems to reduce cost and primary energy consumption, and to improve overall system performance. When comparing the overall performance of coupling photovoltaic thermal with desalination systems, it showed better efficiency than the desalination systems coupled with separate photovoltaic panel and/or solar thermal collector from the energy consumption point of view. The stored thermal energy using heat recovery from the PVT panels is a good way to produce fresh water during the times of the off sun shine. Storage of thermal energy from the PVT panel (or) an electric heater powered by the PVT panel in the basin of solar still provides the opportunity for standalone desalination during off sunshine hours. They concluded that photovoltaic thermal/concentrated photovoltaic thermal coupled solar stills are more self-sustainable and suitable for standalone desalination in remote locations than all other models of solar stills.
Another option is to have the PV connected to the electric power grid,43 as the central-grid PV systems configuration is evaluated to be more viable than the off-grid PV systems. In this case, the PV capacity is to be increased and extra energy to be sold to the grid and to get the energy back from the grid during the periods for which solar radiation is low. This solution is sending all produced PV electricity to the grid and running the RO from the grid.44 This solution is seen as the best among the solutions in case the grid is close to be connected to. In this case, batteries are not connected with PVs because of their high capital and running costs that will increase the LCW. Generally, partial preheating of feed water improves the RO performance; however, most of the PV–RO systems do not have to use the feed water preheating technique whereas most of the solar ORC (Organic Rankine Cycle)-RO use it benefiting from the heat rejection from the ORC. However, when the energy recovery device (ERD) is used, the pre-heating of feed water is not required. Most of the implemented RO plants are driven by PV, because it is still having the lowest cost so far. As for the Research & Development (R&D) in RO, there is a need to redesign new types of membranes to increase their effectiveness. In addition, the disposal of the brine in many desalination systems is an important issue as it affects the aquaculture and the environment.
Silva Pinto et al.45 presented a review over the cost determinants: site selection (location near the source of feed water, cost of energy) and complete system selection, feedwater quality (salinity, level of treatment, type of desalination process required, extent of pre-treatment needed, organic load), and operation and maintenance (O&M) costs. It was found that the hybrid technologies may be dominant and under special conditions can offer increased and more stable production of potable water.
Eltawil et al.46 presented a deep study comparing the different RE technologies that powered many desalination systems. The authors found that plant costs are varied according to: (1) the quality of inlet water (as the lower concentration of TDS in feedwater requires less consumed energy for the treatment process compared to higher TDS in the inlet water); (2) the plant capacity where it affects the size of treatment units; (3) pumping; (4) water storage tanks and water distribution system and (5) site characteristics. Pumping cost and pipe line installation costs can be reduced if the water source and discharge point are near to the plant site. Other factors are related to water intake, pre-treatment, and local/state regulatory requirements. Difference between brackish and sea water desalination is mainly the pumping energy consumption. Membrane replacement costs and maintenance are relatively small. The study showed that the usage of wind in conjunction with the membrane process in desalination would result in lower energy consumption than that with PV. When applying to brackish water desalination, RO and ED powered by wind turbines are usually the best selection. In addition, RO is considered to be the cheapest option when considering low and high production capacities when compared to other technologies. A recent study11 discussed the life cycle cost (LCC) for dilution desalination systems in off-grid locations, where water reuse could be integrated with seawater desalination technology. The economic analysis in this study involved the life cycle assessment (LCA) models that compare baseline RO desalination and other two proposed alternative membrane processes, namely, hybrid FO–RO and UF–RO. The LCA consists of three different assessments, each involving capital expenditure (CAPEX) and operational expenditure (OPEX) presented in the net present value (NPV) and total water cost (TWC). The economic parameters are considered to calculate TWC per cubic metre of water produced every 365 days of drinking water production at 100 m3 per day for the 20 year lifetime of the project. Operational expenditure comprised energy, labour, maintenance, and cleaning costs, including membrane replacement costs and the chemical costs involved in the cleaning procedure. The LCC analyses were conducted for commercial-scale dilution desalination systems on a remote island in Australia. The results indicate that an FO–RO system costs less to produce water than a UF–RO system (2.88 and 2.91 AU $ per m3, respectively). The two proposed dilution desalination systems are comparable to standalone SWRO (3.10 AU $ per m3) with a higher CAPEX (11% and 13%, respectively for FO–RO and UF–RO) resulting from an extra membrane to pre-treat the low-pressure SWRO system. The reduction in OPEX due to the energy savings in dilution desalination was quantified as 7% and 6% lower in FO–RO and UF–RO, respectively.
The direct usage of PV field as a power source for producing cooling and desalination is quite difficult mainly because of the type of motors that are less powerful in DC current. However, the coupling can be made easily with the use of electrical batteries.47 In addition, the PV requires frequent cleaning and maintenance from moisture, soiling in villages and power dumping or shutdown for peak load management in solar thermal and PV. PV requires high solar light (global radiation) for generation of electricity. However, high heat or high temperature and high relative humidity reduce the PV performance.48 New materials for PV that are independent of temperature are needed.
The cost of power generation though PV is high compared to the conventional method. However, this cost can be compensated by environmental benefits. This leads to installation of a greater number of PV and hence larger space.49
Charcosset50 showed that the RE such as solar, wind, and wave could drive membrane processes including RO, MD and ED. Each type of RE has its own advantages that make it suitable to certain applications. Usually, they do not release gaseous or liquid pollutants during their operation. In their technological development, the RE range from technologies that are well established and mature to those that need further research and development.
Hassan et al.53–56 investigated the performance of many sunshine-based models for Egypt to estimate the expected monthly average global solar radiation on a surface horizontally adjusted. The model was developed with the aid of some measured existed data either for globally recognized solar radiation and other meteorological measurements from the existing local stations. The importance of this study is to determine the performance of these models and evaluate them using the most common standard statistical indicators. The analyses suggested that Robaa Model (All Egypt formula) is the most accurate for forecasting the global solar radiation among all other global solar models of Egypt under investigation. While sun-shine based models demonstrate accurate estimation for exploring meteorological data, they are difficult for the practical applications in the sites where these data are not available. Other meteorological parameters like terrestrial temperature can be applied to the present new models in other studies as alternatives to the widely used sunshine-based models when Sun radiation data are unavailable.
Elsayed et al.57 investigated the total interpretation of a large number of models (31) for the estimation of the monthly averaged daily global solar radiation based on a horizontal surface. To make accurate evaluation, over 20 years of the measured global solar radiation data in the location of New Borg El-Arab city (latitude 30° 51′ N and longitude 29° 34′ E) are used for the validation of the models. These models are divided into six different categories. InciTürkToğrul model and Can Ertekin model, which are based on extra-terrestrial radiation and solar declination, showed the best performance.
The Mediterranean Sea coast has a mean wind speed ranging between 2 and 6 m s−1.58 Most of the modern wind turbines usually operate on a horizontal axis mode, but vertical-axis turbines can also be used in some applications, as shown in Fig. 4. An advantage of the vertical-axis turbines is that they do not have to be manually or digitally oriented towards the wind, but rather can utilize wind from any direction without adjustments.
Fig. 4 A sketch representing the common structure of horizontal- and vertical-axis wind turbines (adapted/reproduced from ref. 61 with permission from Elsevier, copyright no. 5032730321770). |
In Egypt, the potential of wind energy should be pushed for the paving desalination technologies, which consume a lot of electrical power such as RO systems. Present onshore wind power cost reached about 0.053 $ kW−1 h−1 according to IRENA estimation in 2019 that are compatible for the application of desalination processes59
The choice for the combinations of RE desalination systems is defined by feed water quality (salinity) and the requirements for product water. Overall a wind powered RO plant is considered to be the most cost-efficient.60
Wind-powered RO plants have been implemented in Croatia,63 Norway (ENERCON project),64 and Australia.65 Feron, et al.,66 developed a theoretical study and concluded that the economic use of a wind-powered RO plant may be restricted to areas with high wind speeds and high fuel prices. He demonstrated the economic feasibility of the wind-powered RO desalination systems in the cases of decreasing RO plant cost with the continuous development of membrane technologies, decreasing wind turbine and system costs as well as steady or decreasing fossil fuel costs. Kiranoudis et al.67 concluded that the unit cost of freshwater production by a conventional RO plant powered by wind turbines can be reduced up to 20% for regions with an average wind speed of 5 m s−1 or higher.
A small-scale wind-powered RO desalination system was constructed and tested in Hawaii, for the brackish water desalination.68 These authors showed that at an average wind speed of 5 m s−1, brackish feedwater at a total dissolved solid concentration of 3000 mg l−1 at a flow rate of 13 l min−1 could be processed. The average rejection rate and recovery ratio were 97% and 20%, respectively.
A lot of RE powered units such as PV/RO are limited to small-scale desalination systems and have varying specific energy consumption values ranging from 1.1 to 16 kW h m−3.70 Solar energy source is variable and unavoidable to be faced, and thus efficient storage means, and batteries are required to tackle this problem. For remote locations, instead of RO, the use of PV is also attractive for electro-dialysis where BW is readily available throughout a year.
Other hybrid solar PV-wind desalination systems proved to be implemented and run under different circumstances. A hybrid solar PV-wind power plant used for the supply of electricity for RO desalination system was constructed in Libya's coast.71,72 The nominal production of the plant was intended to be 300 m3 per day for the supply of a village with potable water. The plant design was integrated to a back-up diesel generator and electrochemical storage systems in combination with the hybrid RE system. In another configuration, Mohamed and Papadakis73 presented a different design of a stand-alone hybrid wind-PV-wind system to power a SWRO desalination unit, with energy recovery using a simplified spreadsheet model. Daily and monthly simulation and economic analyses were also performed. The calculated fresh water production cost was estimated to be 5.2 € per m3, and the realized energy saving was close to 50% when a pressure-exchanger-type energy recovery unit was considered.
Henderson et al.74 showed that seawater desalination using RO is an attractive choice because of the low specific energy consumption, typically around 10 kW h m−3 of water for a small unit.
The problem with RO is its sensitivity to fluctuating power. Fadigas and Dias75 used a hybrid system that uses both gravitational potential energy and wind energy. The economic viability is supported, not only by the fact that the model uses a renewable “free” source of energy, but also because of a predicted low specific consumption of energy of around 2.811 kW h m−3). Kroiß A. et al.76 discussed the benefits of the combination of RO systems with PV/T systems as the RO fresh-water output is increased at elevated seawater temperatures. However, the PV efficiency is increased due to cooling with seawater. In addition, a seawater-proof system was presented. This study included experimental investigation on a PVT prototype.
A team from Tunisia, Jordan and Spain made a study on the control of PV/T-based RO desalination plant.77 The control of the circulated fluid rate improves the system productivity. The feed water temperature is raised by the utilization of the recovery of the PVT-produced heat for feed water preheating in order to improve the RO productivity. The system control aimed to prevent overheating of the PV solar modules. A fuzzy logic controller was designed to achieve these objectives. The controller effectiveness was validated using LABVIEW.
Hybrid renewable energy systems (HRES) are systems that combine two or more renewable energy resources. Khan et al.78 discussed the modelling of the electrical components of the HRES such as modelling of the PV system, the modelling of the wind system, the battery, the generator, the RO system, modelling and the performance of a hybrid PV and wind RO system. In addition, the sizing and economics of an HRES-RO system was presented. An economic analysis of desalination of solar- and wind-driven plants was conducted and showed an improvement in the prospects for solar desalination technology and produced water cost reduction. The cost is affected by several factors including the solar radiation and level of salinity. In the case of using Wind-RO technology, the cost of the produced water depends on wind speed, feed water total dissolved solids (TDS) and the capacity of the desalination plant.
Several challenges face the RE desalination systems. Some of these challenges were given by ref. 47. The first challenge for coupling desalination with cooling systems is the need for the centralized cooling system to make the system more efficient and economical. Thus, it is recommended to implement the coupling of centralized cold storage and water production. The second challenge is the need to develop an intelligent management and control system between energy and desalination output to achieve an optimized system.
Abou Rayan et al.58 showed that desalination using RE does offer the potential of providing a sustainable source of potable water for some communities, particularly those in arid areas. The successful renewable energy desalination system/desalination applications prove that the coupling of two technologies (PV and wind energy) is technically mature and capable of providing fresh water at a reasonable cost using RO.
Another bright side of using RE is the reduction of the greenhouse gasses (GHG), which is related to the climate change. Multiple studies have been performed to investigate the impacts of using fossil fuel on climate change and global warming in Egypt.79,80
A developed project by A. Kassem et al.81 was executed for the construction of Hybrid RE systems for the supply of services for the rural settlements of Mediterranean partner countries in 2008 via the HYRESS Project of FP6 Project funded by EU.
In another project that was funded by STIFA, a 30 m3 per day RE-driven RO desalination plant was designed and installed in Wadi Al-Natroon site. The plant was used to study the effect of different levels of the four plant’ main input variables, namely, the feed water flow rate, concentration, pressure and temperature on five system performance indicators, namely, the system water permeation rate, brine flow rate, recovery ratio, concentration (polarization) factor, and specific energy.81
Numerous studies investigated the use of hybrid RE to power the desalination processes. A study was presented in 2013 (ref. 82) that aimed at making a numerical model that would allow finding the optimal design of a hybrid solar-wind source of energy to operate a small-sized RO desalination plant. The optimum parameters for the design included a number of PV modules, wind turbines capacities, the wind tower height, the rotor blade radius, and total capacity of the desalination plant. The aim was to optimize these parameters to obtain the minimum cost of the produced fresh water. The RO unit would have to produce the required monthly water demand needs to a small community (of 100 people) powered by the hybrid solar-wind system. The results indicated that water can be produced at a cost ranging from 0.498, 0.851 to 1.211 $ per m3 for the three specific energy consumptions, respectively using the design parameters in this case-study.
Another study of a RE power-driven high-performance MSF desalination unit integrated with nano-filtration (NF) membrane was presented by Abdel Nasser et al.83 The pilot test unit was constructed to calculate the performance of the novel de-aeration and brine mix (MSF-DBM) configuration. The NF was added to enable the MSF desalination unit to operate at a high top brine temperature (TBT) of 130 °C. The capacity of the desalination pilot plant was 1.0m3 per day of desalinated water. The plant was installed at Wadi El-Natroun (Egypt). The study found that the high-performance NF-MSF-DBM and unit's input thermal energy which make the integration with (the relatively expensive) RE as a desalination plant driver is a viable option.
City for Scientific Research Technological Applications (SRTA-City) in Borg El-Arab, Egypt is holding several research projects that are related to desalination and RE. One of these running large projects is Multipurpose Applications by Thermodynamic Solar (MATS) project, which is funded by European Frame-Work Projects (FP7) and Egyptian Academy of Scientific Research and Technology (ASRT).84 This Mega R&D project is a full-scale demonstration of Concentrating Solar Power (CSP) technology through the industrial development, the realization and the experimental operation of a multipurpose facility to be installed in Egypt. The facility is designed to produce 1.0 MW of electricity and 250 m3 per day of desalinated water. This project was a big collaboration between 11 international partners and 8 Egyptian partners to contribute in both the R&D and installation phases of the CSP power plant. The MATS plant layout is shown in Fig. 5a, which shows the solar field that has a total 10000 m2 active area.85
Fig. 5 MATS project, (a) Google Earth Image of MATS layout demonstrating three stages of the solar field (December 2017),84 (b) MATS main components illustrating the combination of steam generators with heat storage systems located at SRTA-City, Egypt. |
MATS system uses combined solar field and gas-powered back up unit, to provide the required heat to be stored in the TES (Thermal Energy Storage tank) with the built-in steam generator (SG) system, as shown in Fig. 5b. In the MATS system, molten salts (MS) loop is uninterruptedly pumped from the bottom of the TES tank through the MS pump to the zones of the solar field. Under normal operation, the designed bottom temperature of the MS in the TES tank is 290 °C in order to maintain the MS in liquid phase. MS exits the solar field at a given temperature depending (in general) on the incoming solar radiation (DNI) and the overall efficiency/cleanness of solar collectors. The objective is to keep this exit temperature constant at a design value of 550 °C. Thus, the MS flow rate in the solar field is adjusted in order to obtain this exit temperature: the lower the DNI value and solar collectors' efficiency/cleanness, the lower the applied MS flow rate in the solar field. The inlet MS temperature of the top of the TES tank is kept stable at 550 °C. During normal operation, the steam generator (SG) is fed with liquid water to generate a superheated steam. Thermal power will be provided by the MS re-circulating inside the TES tank. Steam turbine is fed with superheated steam discharged as non-condensed steam. Under these conditions, a steam turbine connected to an electrical generator will produce the gross power of 1.0 MWe. The steam rejected by the turbine is sent to the two-effects MED desalination unit, where the steam is condensed to sustain 250 m3 per day demi-water production. Thermal duty of the MED will be provided by turbine back pressure steam condensation. It is noteworthy that in this steam Rankine cycle, the MED unit works as a condenser. This proof of concept pilot project will allow testing the CSP (concentrating solar power) technology in a location very advantageous regarding the solar radiation rate as an example for the diffusion of this technology in other Mediterranean countries.85
Another on-going project is to develop a greenhouse-desalination system self-productive of energy and irrigating water, which is funded by STDF in Egypt according to the scheme of the National Challenge Program (NCP). The main objective of this project is to develop, design and pilot testing of an innovative and cost-effective agriculture greenhouse (GH) that grows its own energy and irrigating water demand. The new GH utilizes the surplus solar energy (above that required for the plants' photosynthetic process) to produce the required irrigation water via direct solar distillation (solar stills) units. In addition, the ventilation air humidity will be partially recovered before leaving the GH to gain additional fresh water via a humidification de-humidification (HDH) desalination system. The GH will also be equipped with a vertical thermal chimney to naturally circulate/ventilate the system and minimize its O&M and cost. A novel automated smart control framework will be integrated with the GH in order to control all its vital parameters (Table 2). The proposed control framework employs a smart artificial intelligence unit that processes the real-time distributed sensor feedback to dynamically adjust the GH climate, fertilization-process and irrigating water-treatment towards the best interest of the enclosed crops and plants. The target is to provide the GH with controlled microclimatic conditions that suit the optimum plant productivity. Both the numerical results and the experimental measurements from the pilot test unit will allow the investigation of the developed system's operational performance under controlled internal microclimatic conditions. The validated programs and experimental results will be used to develop the conceptual design of “commercial system” that suits different operating conditions for the innovative greenhouse.
Point | Description of the operation parameter |
---|---|
1 | Brackish saline water feed, 20000 ppm, T = 15 °C. |
2 | Pre-heated inlet saline water, 20000 ppm, T = 15–30 °C |
3 | Pre-treated inlet saline water, T = 15–30 °C |
4 | RO brine rejection, 40000 ppm, T = 15–30 °C |
5 | RO brine rejection, 40000 ppm, T = 20–35 °C |
6 | RO brine rejection, 40000 ppm, T = 55–65 °C |
7 | RO brine rejection, 40000 ppm, T = 70–80 °C |
8 | MD brine rejection, 45000 ppm, T = 35–40 °C |
9 | MD brine rejection, 45000 ppm, T = 25–30 °C |
10 | RO product water, 250–350 ppm, T = 15–30 °C |
11 | MD product water, 50 ppm, T = 25–30 °C |
12 | Product water, 300 ppm, T = 15–30 °C |
13 | PV/T hot stream, T = 60–70 °C |
14 | PV/T coldstream, T = 25–35 °C |
Salah et al.86 investigated the performance of the above stand-alone agriculture greenhouse (GH) integrated with on-roof transparent solar stills (TSS) to be self-sufficient of irrigation water. For different climatic conditions of New Borg El-Arab, Egypt, controlling both the condenser bypass and fresh air ratios can be used to satisfy the required micro-climate conditions and water requirements for plant growth and minimize the power consumption for the cooling system. The system produces insufficient amount of water during the coldest day, which indicates the need for additional solar stills to be installed for supplying a large quantity of water.
However, an ongoing project at SRTA-City through Egypt-UK Newton-Musharafa Fund: Institutional Links, STIFA Project ID 26214 aims to develop, design and pilot test an innovative RE driven–hybrid desalination technology for remote areas. The driving RE electrical & thermal energies will be generated using integration of PVT and wind turbine units. A hybrid desalination process integrating RO and MD will be developed. An integrated hybrid power-hybrid desalination system will be designed to suit small communities in remote areas in Egypt such as Sinai, North West, Red sea coasts and isolated desert areas. The project involves the development of precise numerical models followed by a detailed design of 5.0 m3 per day pilot test unit (Fig. 6), leading to the development of a standard commercial small-scale unit for small community use. The collaboration will have immense impact in terms of; (i) providing clean water to remote areas at a lower cost, and (ii) opening up further research avenues in desalination and green energy. A recent published article87 demonstrated the design and numerical model activities for the development of the desalination system of an off-grid solar energy-powered RO for continuous production of freshwater with PVT cooling and the recovery of the PVT cooling heat for RO feedwater pre-heating. This work aimed to quantify the increase in the efficiency of PV cells and RO desalination for the application of seawater as the cooling medium for PV. A battery unit is included to ensure continuous production of the desalinated water. A reduction of 0.12 kW h m−3 in the energy consumption is achieved leading to a 6% reduction in the required solar panel surface area.
AGMD | Air gap membrane distillation |
BW | Brackish water |
CCPWD | Capillary channel plasmonic water desalination |
CPV | Concentrated photovoltaic |
CSP | Concentrating solar power |
DC | Direct current |
DCMD | Direct contact membrane distillation |
DNI | Direct normal irradiances |
DO | dissolved oxygen |
ED | Electro-dialysis |
elc | Electrical |
ERC | Energy recovery device |
FO | Forward osmosis |
GHI | Global horizontal irradiances |
HDH | Humidification-dehumidification |
HRES | Hybrid renewable energy systems |
IRENA | International renewable energy agency |
LCW | Levelized cost of water |
MENA | Middle East and North Africa |
MED | Multiple effect distillation |
ME-AD | Multi-evaporator adsorption |
MED-AD | Multiple effect distillation-adsorption distillation |
MD | Membrane distillation |
MF | Micro filtration |
MATS | Multipurpose applications by thermodynamic solar |
MO | Molten salts |
MSF | Multi stages flash |
NF | Nano filtration |
NREA | National Renewable Energy Authority |
O&M | Operation and maintenance |
ORC | Organic Rankine cycle |
pe | Primary energy |
PV | Photovoltaic |
PVT | Photovoltaic thermal |
PFD | Process flow diagram |
ppm | part per million |
RE | Renewable energy |
R&D | Research & development |
RO | Reverse osmosis |
SGMD | Sweep gas membrane distillation |
STIFA | Science, technology and innovation funding authority |
SG | Steam generator |
SWRO | Sea water reverse osmosis |
TBT | Top brine temperature |
TDS | Total dissolved solids |
UF | Ultra-filtration |
UPR | Universal performance ratio |
VC | Vapor compression |
VMD | Vacuum membrane distillation |
WHO | World health organization |
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