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Correction: Uncovering diverse reactivity of NHCs with diazoalkane: C–H activation, C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e001.gif)
C bond formation, and access to N-heterocyclic methylenehydrazine
Kajal
Balayan
ab,
Himanshu
Sharma
bc,
Kumar
Vanka
bc,
Rajesh G.
Gonnade
*bc and
Sakya S.
Sen
*ab
aInorganic Chemistry and Catalysis Division, CSIR-National Chemical Laboratory, Dr Homi Bhabha Road, Pashan, Pune 411008, India. E-mail: ss.sen@ncl.res.in
bAcademy of Scientific and Innovative Research (AcSIR), New Ghaziabad 201002, India
cPhysical and Material Chemistry Division, CSIR-National Chemical Laboratory, Dr Homi Bhabha Road, Pashan, Pune 411008, India. E-mail: rg.gonnade@ncl.res.in
First published on 21st May 2025
Abstract
Correction for ‘Uncovering diverse reactivity of NHCs with diazoalkane: C–H activation, C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
C bond formation, and access to N-heterocyclic methylenehydrazine’ by Kajal Balayan et al., Chem. Sci., 2024, 15, 18387–18394, https://doi.org/10.1039/D4SC05740F.
The authors regret that there is an error in the previously published version of Fig. 12. The structure was inadvertently labelled as COOEt, whereas it should be COOtBu. However, all calculations were performed using COOtBu, so the reported energy values remain unchanged. The corrected scheme is shown below. This correction does not affect any of the conclusions presented in the work.
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| Fig. 12 The free energy profiles for the formation of compound 13 and compound 14 have been shown here. All values are in kcal mol−1. Level of theory: PBE0-D3/def2TZVP//PBE-D3/defTZVP with solvent toluene. | ||
The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
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