The molecular structure of a new compound, (h5-C5H5)(NO2)Mn(1)(µ-NO)2Mn(2)(NO)(h5-C5H5), has been determined by X-ray crystallography, in which the most striking feature is the presence of highly unsymmetrical NO bridges: N–Mn(1)= 1·775(4)Å N–Mn(2)= 1·943(4)Å; a probable structure for (C5H5)3Mn2(NO)3 can be inferred from the structure here reported.
J. L. Calderon, F. A. Cotton, B. G. DeBoer and N. Martinez, J. Chem. Soc. D, 1971, 1476 DOI: 10.1039/C29710001476
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