Dihydromancunine (2a), a model for a proposed biosynthetic intermediate, has been synthesised from vincoside and converted into Corynanthé indole alkaloids in a biomimetic sequence; hirsutine (6b) and dihydrocorynantheine (6c) have also been synthesised.
R. T. Brown, C. L. Chapple and A. A. Charalambides, J. Chem. Soc., Chem. Commun., 1974, 756 DOI: 10.1039/C39740000756
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