The reversible reaction[W(η-C5H5)2(PR3)CD3]+⇌[W(η-C5H5)2(CD2PR3)D]+ and related reactions are described; it is proposed that they proceed via a reversible equilibrium W–CH3⇌ W(![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH2)H.
N. J. Cooper and M. L. H. Green, J. Chem. Soc., Chem. Commun., 1974, 761 DOI: 10.1039/C39740000761
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