The complex PtCl[PEt3]3+ does not react with chloride to form cis or trans PtCl2[PEt3]2 and when a different phosphine is used to catalyse the cis–trans isomerization ofPtCl2[PEt3]2, the phosphines do not mix during isomerization; these data contradict the consecutive displacement mechanism.
W. J. Louw, J. Chem. Soc., Chem. Commun., 1974, 353a DOI: 10.1039/C3974000353A
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