With the metathesis catalyst W(CO)5L·AlBr3, AlBr3 acts first as a Lewis acid to give a 1 : 1 adduct which further yields a co-ordinatively unsaturated, relatively stable zerovalent tungsten.
Y. B. Taarit, J. L. Bilhou, M. Lecomte and J. M. Basset, J. Chem. Soc., Chem. Commun., 1978, 38 DOI: 10.1039/C39780000038
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