NN-Dimethylsulphamate esters react with methyl fluorosulphate to give trimethylammoniosulphate esters; the phenyl ester (2) is readily characterized, but alkyl esters immediately give fluorosulphate esters or elimination products, showing that trimethylammonio-sulphate is a very powerful leaving group.
J. F. King and T. M. Lee, J. Chem. Soc., Chem. Commun., 1978, 48 DOI: 10.1039/C39780000048
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