The dimeric d9 PdI dianion [Pd2Cl4(CO)2]2– is shown to have two bridging carbonyl ligands both in the solid state and in solution by X-ray structure analysis and i.r. spectroscopy; this is in contrast with a large number of d8 di- and polymeric metal carbonyl halide complexes where the halide ligands are bridging.
P. L. Goggin, R. J. Goodfellow, I. R. Herbert and A. G. Orpen, J. Chem. Soc., Chem. Commun., 1981, 1077 DOI: 10.1039/C39810001077
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...