Issue 20, 1981

ipso-Attack in the hydroxylation of o- and p-xylene using bis(trimethylsilyl) peroxide and aluminium chloride

Abstract

Electrophilic hydroxylation of o- and p-xylene using a range of peroxides, including the title compound, in the presence of Lewis acids results in the formation of mixtures of phenols including those derived by ipso-attack followed by rearrangement; ipso-attack by the hydroxyl radical leads to dealkylation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1079-1080

ipso-Attack in the hydroxylation of o- and p-xylene using bis(trimethylsilyl) peroxide and aluminium chloride

J. O. Apatu, D. C. Chapman and H. Heaney, J. Chem. Soc., Chem. Commun., 1981, 1079 DOI: 10.1039/C39810001079

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