Issue 7, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and characterisation (by X-ray crystallography) of di-azido-and di-S-thiocyanato-di-µ-methylene-bis (pentamethylcyclopentadienyl) dirhodium and related molecules

Kiyoshi Isobe,   Pamela M. Bailey,   Peter Schofield,   J. Trevor Gauntlett,   Andrew Nutton  and  Peter M. Maitlis  

Abstract

cis and trans-[(C5Me5Rh)2(µ-CH2)2(CH3)2] react with HCl to give trans-[(C5Me5Rh)2(µ-CH2)2Cl2] which gives trans-[(C5Me5Rh)2(µ-CH2)2X2] with NaX, trans-[(C5Me5Rh)2(µ-CH2)2Et2] with Et3Al, and cis-[(C5Me5Rh)2(µ-CH2)2(O2CMe)]+ with NaOAc; X-ray determinations of [(C5Me5Rh)2(µ-CH2)2X2](X = N3 and SCN) confirm the structures.

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Article information

DOI
https://doi.org/10.1039/C39820000425
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 425-426

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Synthesis and characterisation (by X-ray crystallography) of di-azido-and di-S-thiocyanato-di-µ-methylene-bis (pentamethylcyclopentadienyl) dirhodium and related molecules

K. Isobe, P. M. Bailey, P. Schofield, J. T. Gauntlett, A. Nutton and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1982, 425 DOI: 10.1039/C39820000425

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