Issue 4, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

β-C–H interaction vs. Dihaptoacyl co-ordination in a molybdenum acetyl complex. X-Ray crystal structure of [Mo(Ac)(S2CNMe2)(CO)-(PMe3)2]

Ernesto Carmona,   Luis Sánchez,   Manuel L. Poveda,   José M. Marín,   Jerry L. Atwood  and  Robin D. Rogers  

Abstract

N.m.r. and X-ray studies of the title compound, obtained from [MoCl(η2-COCH2SiMe3)(CO)(PMe3)3] and NaS2CNMe2 in aqueous acetone, indicate that molybdenum atom attains an 18-electron configuration by interacting with a β-C–H bond [Mo–C 2.60(1), Mo–H 2.06(9)Å] rather than by dihapto co-ordination to the acetyl group.

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Article information

DOI
https://doi.org/10.1039/C39830000161
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 161-162

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β-C–H interaction vs. Dihaptoacyl co-ordination in a molybdenum acetyl complex. X-Ray crystal structure of [Mo(Ac)(S2CNMe2)(CO)-(PMe3)2]

E. Carmona, L. Sánchez, M. L. Poveda, J. M. Marín, J. L. Atwood and R. D. Rogers, J. Chem. Soc., Chem. Commun., 1983, 161 DOI: 10.1039/C39830000161

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