Bilirubin (1) bound to human serum albumin undergoes an asymmetric photocyclization to give optically active (2), which exhibits bisignate long-wavelength circular dichroism.
A. F. McDonagh, D. A. Lightner, M. Reisinger and L. A. Palma, J. Chem. Soc., Chem. Commun., 1986, 249 DOI: 10.1039/C39860000249
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