The size of Ru crystallites affected markedly the selectivity for CO hydrogenation in contrast to previous reports; small particles (10 Å) produced significant proportions of higher hydrocarbons and large single crystallites (110 Å) gave mainly methane.
Z. Lin, T. Okuhara, M. Misono, K. Tohji and Y. Udagawa, J. Chem. Soc., Chem. Commun., 1986, 1673 DOI: 10.1039/C39860001673
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