Formaldehyde has been produced from the oxidation of methane with oxygen on silica at atmospheric pressure and at reaction temperatures between 773 and 873 K, in contrast to the results with nitrous oxide where complete oxidation products are formed.
S. Kasztelan and J. B. Moffat, J. Chem. Soc., Chem. Commun., 1987, 1663 DOI: 10.1039/C39870001663
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