Issue 24, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Electronic control of the co-ordination mode of an alkyne to a trimetallic cluster; X-ray crystal structure of Os3(CO)7(µ3-η2(⊥)-PhC[triple bond, length as m-dash]CPh)(Ph2PCH2PPh2)

Jennifer A. Clucas,   P. Ann Dolby,   Marjorie M. Harding  and  Anthony K. Smith  

Abstract

Treatment of the unsaturated triosmium cluster Os3(µ-H)(CO)8{µ-Ph2PCH2P(Ph)C 6H4} with diphenylacetylene leads to the formation of Os3(CO)7(PhC[triple bond, length as m-dash]CPh)(Ph2PPh2), in which the alkyne ligand is bonded in a µ3-η2(⊥) mode, as shown by an X-ray crystal structure determination.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39870001829
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1829-1831

Permissions

Request permissions

Electronic control of the co-ordination mode of an alkyne to a trimetallic cluster; X-ray crystal structure of Os3(CO)7(µ3-η2(⊥)-PhC[triple bond, length as m-dash]CPh)(Ph2PCH2PPh2)

J. A. Clucas, P. A. Dolby, M. M. Harding and A. K. Smith, J. Chem. Soc., Chem. Commun., 1987, 1829 DOI: 10.1039/C39870001829

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements