Solvolysis of the neopentyl triflates 14, 25 and 32 resulted in ring expansion of a seven-membered ring into the eight-membered ring required for the synthesis of the taxanes diterpenoids.
P. Magnus, L. Diorazio, T. Donohoe, M. Giles, P. Pye, J. Tarrant and S. Thom, J. Chem. Soc., Chem. Commun., 1995, 1935 DOI: 10.1039/C39950001935
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