Issue 2, 2001
From the journal:

Chemical Communications

A remarkable Cr(iii) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion

Rodolphe Clérac,a   F. Albert Cotton,*a   Carlos A. Murillo*a  and  Xiaoping Wanga  

* Corresponding authors

a The Laboratory for Molecular Structure and Bonding, Department of Chemistry, Texas A&M University, PO Box 30012, College Station, TX, USA.
E-mail: cotton@tamu.edu; murillo@tamu.edu

b Department of Chemistry, University of Costa Rica, Ciudad Universitaria, Costa Rica

Abstract

In addition to a quadruply bonded dichromium(II,II) compound of unusual structure, we have obtained a dinuclear, antiferromagnetically coupled, CrIII complex [Cr2(μ-OMe)2(η3-N,C,N′ -H2DpyF)2Cl2·MeOH, H2DpyF = CH(NH-pyridyl)2] containing a transformed formamidinate group in which the central carbon atom has changed from sp2 to sp3 hybridization and Cr–C bonds have been formed; details of the crystal structure of the organometallic compound are given here.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B007813L
Article type
Communication
Submitted
11 Aug 2000
Accepted
06 Dec 2000
First published
09 Jan 2001

Chem. Commun., 2001, 205-206

Permissions

Request permissions

A remarkable Cr(III) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion

R. Clérac, F. A. Cotton, C. A. Murillo and X. Wang, Chem. Commun., 2001, 205 DOI: 10.1039/B007813L

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements