Reactions of laser-ablated gold atoms with H2O2 and H2 + O2 mixtures give four new infrared absorptions, which match the four most intense vibrational frequencies calculated for Au(OH)2 using density functional theory; the calculations find a C2h structure and substantial covalent bonding character for the Au(OH)2 molecule, which is probably due to the high electron affinity of gold.
X. Wang and L. Andrews, Chem. Commun., 2005, 4001 DOI: 10.1039/B506970J
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