Issue 25, 2006
From the journal:

Chemical Communications

First C-3 lithiation of DMAP: a new entry into chemical tuning of acylation catalysts†

Philippe C. Gros,*a   Abdelatif Doudouha  and  Christopher Woltermannb  

* Corresponding authors

a Synthèse Organométallique et Réactivité, UMR CNRS-UHP 7565 Université Henri Poincaré, Faculté des Sciences, Boulevard des Aiguillettes, 54506 Vandoeuvre-lès-Nancy, France
E-mail: philippe.gros@sor.uhp-nancy.fr
Fax: +33 3836 84785
Tel: +33 3836 84979

b FMC Corporation, Lithium Division, Highway 161 Box 795, Bessemer City, NC, USA
E-mail: CHRIS_WOLTERMANN@fmc.com
Fax: +1 704 868 5496
Tel: +1 704 868 5421

Abstract

A TMSCH2Li-based reagent promoted the first C-3 lithiation of DMAP opening a direct access to functional diversity in acylation catalysts.

Graphical abstract: First C-3 lithiation of DMAP: a new entry into chemical tuning of acylation catalysts

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Article information

DOI
https://doi.org/10.1039/B605170G
Article type
Communication
Submitted
11 Apr 2006
Accepted
09 May 2006
First published
22 May 2006

Chem. Commun., 2006, 2673-2674

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First C-3 lithiation of DMAP: a new entry into chemical tuning of acylation catalysts

P. C. Gros, A. Doudouh and C. Woltermann, Chem. Commun., 2006, 2673 DOI: 10.1039/B605170G

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