Issue 46, 2007
From the journal:

Chemical Communications

Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies†

Sanjay Singh,a   Jianfang Chai,a   Aritra Pal,a   Vojtech Jancik,a   Herbert W. Roesky*a  and  Regine Herbst-Irmera  

* Corresponding authors

a Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany
E-mail: hroesky@gwdg.de

Abstract

The first examples of base free lithium-organoaluminate and the corresponding gallium compound [LM(Me)OLi]3 (M = Al (3), Ga (4); L = HC{C(Me)N-2,6-iPr2C6H3}2) have been prepared by the reaction of Li[N(SiMe3)2] with the corresponding metal hydroxides LM(Me)OH (M = Al (1), Ga(2)); the oxygen atom in the M–O–Li fragment exists as oxide ion and is involved in the central Li3O3 six-membered ring formation.

Graphical abstract: Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies

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Article information

DOI
https://doi.org/10.1039/B712240C
Article type
Communication
Submitted
09 Aug 2007
Accepted
11 Oct 2007
First published
29 Oct 2007

Chem. Commun., 2007, 4934-4936

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Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies

S. Singh, J. Chai, A. Pal, V. Jancik, H. W. Roesky and R. Herbst-Irmer, Chem. Commun., 2007, 4934 DOI: 10.1039/B712240C

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