Issue 1, 2009
From the journal:

CrystEngComm

Self-assembly of a novel metal–organic coordination cage (MOCC) based on a new flexible dicarboxylate ligand: synthesis, crystal structure and magnetic property†

Fangna Dai,a   Haiyan He,a   Aiping Xie,a   Guodong Chu,a   Daofeng Sun*a  and  Yanxiong Ke*b  

* Corresponding authors

a Key Lab for Colloid and Interface Chemistry of Education Ministry, Department of Chemistry, Shandong University, Jinan, P. R. China
E-mail: dfsun@sdu.edu.cn
Fax: +86 53188364218
Tel: +86 53188364218

b Engineering Research Center of Pharmaceutical Process Chemistry, Ministry of Education, School of Pharmacy, East China University of Science and Technology, 130 Meilong Road, Shanghai, P. R. China
E-mail: key@ecust.edu.cn

Abstract

The self-assembly of flexible bended dicarboxylate ligand, 2,2′-(2,4,6-trimethyl-1,3-phenylene)bis(methylene)-bis(sulfanediyl)-dibenzoic acid (H2L), with Mn(OAc)2·4H2O resulted in the formation of a novel metal–organic coordination cage with binuclear manganese SBU as the vertex, which represents the first metal–organic coordination cage constructed from a flexible dicarboxylate ligand and a binuclear SBU.

Graphical abstract: Self-assembly of a novel metal–organic coordination cage (MOCC) based on a new flexible dicarboxylate ligand: synthesis, crystal structure and magnetic property

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Article information

DOI
https://doi.org/10.1039/B816015P
Article type
Communication
Submitted
12 Sep 2008
Accepted
30 Sep 2008
First published
04 Nov 2008

CrystEngComm, 2009,11, 47-49

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Self-assembly of a novel metal–organic coordination cage (MOCC) based on a new flexible dicarboxylate ligand: synthesis, crystal structure and magnetic property

F. Dai, H. He, A. Xie, G. Chu, D. Sun and Y. Ke, CrystEngComm, 2009, 11, 47 DOI: 10.1039/B816015P

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