Issue 7, 2010
From the journal:

Chemical Communications

Microscale hexagonal rods of a charge-assisted second-sphere coordination compound [Co(DABP)3][Fe(CN)6]†

Fuyu Zhuge,ad   Biao Wu,*ab   Jin Yang,b   Christoph Janiak,c   Ning Tangb  and  Xiao-Juan Yang*ab  

* Corresponding authors

a State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000, China
E-mail: wubiao@lzb.ac.cn, yangxj@lzb.ac.cn
Fax: +86 931 4968286

b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China

c Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstr. 21, D-79104 Freiburg, Germany

d Graduate School of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A second-sphere complex [Co(DABP)3][Fe(CN)6] (1) (DABP = 5,5′-diamino-2,2′-bipyridine) is constructed from [Co(DABP)3]3+ and [Fe(CN)6]3− through charge-assisted N–H(NH2)⋯N(CN) hydrogen bonds; hexagonal microrods of 1 are obtained via a facile self-assembly method in the presence of surfactant.

Graphical abstract: Microscale hexagonal rods of a charge-assisted second-sphere coordination compound [Co(DABP)3][Fe(CN)6]

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Article information

DOI
https://doi.org/10.1039/B914216A
Article type
Communication
Submitted
15 Jul 2009
Accepted
23 Nov 2009
First published
15 Dec 2009

Chem. Commun., 2010,46, 1121-1123

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Microscale hexagonal rods of a charge-assisted second-sphere coordination compound [Co(DABP)3][Fe(CN)6]

F. Zhuge, B. Wu, J. Yang, C. Janiak, N. Tang and X. Yang, Chem. Commun., 2010, 46, 1121 DOI: 10.1039/B914216A

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