Issue 26, 2010
From the journal:

Chemical Communications

Synthesis and theoretical studies of gallium complexes back-shielded by a cage-shaped framework of tris(m-oxybenzyl)arene†

Hideto Nakajima,a   Makoto Yasuda,*a   Kouji Chibab  and  Akio Baba*a  

* Corresponding authors

a Department of Applied Chemistry and Center for Atomic and Molecular Technologies, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
E-mail: yasuda@chem.eng.osaka-u.ac.jp, baba@chem.eng.osaka-u.ac.jp
Fax: +81-06-6879-7387
Tel: +81-06-6879-7386

b Science and Technology System Division, Ryoka Systems Inc., 1-28-38 Shinkawa, Chuo-ku, Tokyo 104-0033, Japan

Abstract

Cage-shaped gallium complexes with a back-shielding framework of tris(m-oxybenzyl)arene were synthesized, their bottom arene rings tuned their characteristic Lewis acidity, which was supported by theoretical calculation as well as catalytic application in a hetero Diels–Alder reaction.

Graphical abstract: Synthesis and theoretical studies of gallium complexes back-shielded by a cage-shaped framework of tris(m-oxybenzyl)arene

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Article information

DOI
https://doi.org/10.1039/C0CC00253D
Article type
Communication
Submitted
06 Mar 2010
Accepted
28 Apr 2010
First published
25 May 2010

Chem. Commun., 2010,46, 4794-4796

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Synthesis and theoretical studies of gallium complexes back-shielded by a cage-shaped framework of tris(m-oxybenzyl)arene

H. Nakajima, M. Yasuda, K. Chiba and A. Baba, Chem. Commun., 2010, 46, 4794 DOI: 10.1039/C0CC00253D

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