Issue 30, 2010
From the journal:

Chemical Communications

Pd-catalyzed cross-coupling of carboxylic acids with nitroethanevia combination of decarboxylation and dehydrogenation†

Min Zhang,a   Jun Zhou,a   Jian Kan,a   Min Wang,a   Weiping Su*a  and  Maochun Honga  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: wpsu@fjirsm.ac.cn
Fax: +86 591 8377 1575
Tel: +86 591 8377 1575

Abstract

An unexpected coupling reaction of arene carboxylic acid with nitroethane via a combination of decarboxylation and dehydrogenation is described. The method provides exclusively (E)-β-nitrostyrenes.

Graphical abstract: Pd-catalyzed cross-coupling of carboxylic acids with nitroethane via combination of decarboxylation and dehydrogenation

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Article information

DOI
https://doi.org/10.1039/C0CC01029D
Article type
Communication
Submitted
20 Apr 2010
Accepted
15 Jun 2010
First published
01 Jul 2010

Chem. Commun., 2010,46, 5455-5457

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Pd-catalyzed cross-coupling of carboxylic acids with nitroethane via combination of decarboxylation and dehydrogenation

M. Zhang, J. Zhou, J. Kan, M. Wang, W. Su and M. Hong, Chem. Commun., 2010, 46, 5455 DOI: 10.1039/C0CC01029D

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