Synthesis, characterization and property of a mixed-valent AgI/AgII coordination polymer

Di Sun; Cheng-Feng Yang; Hao-Ran Xu; Hai-Xia Zhao; Zhan-Hua Wei; Na Zhang; La-Jia Yu; Rong-Bin Huang; Lan-Sun Zheng

doi:10.1039/C0CC02112A

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Synthesis, characterization and property of a mixed-valent Ag^I/Ag^II coordination polymer†

Di Sun,^a Cheng-Feng Yang,^a Hao-Ran Xu,^a Hai-Xia Zhao,^a Zhan-Hua Wei,^a Na Zhang,^a La-Jia Yu,^a Rong-Bin Huang*^a and Lan-Sun Zheng^ab

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* Corresponding authors

^a Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
E-mail: rbhuang@xmu.edu.cn

^b State key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, China

Abstract

A novel mixed-valent Ag^I/Ag^II coordination polymer {[Ag^I₂Ag^II_0.5(SO₄)(HSO₄)(pyz)_2.5]·H₂O}_n (1, pyz = pyrazine) was synthesized and characterized. The results show it presents semiconducting and photoluminescent properties.

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Article information

DOI: https://doi.org/10.1039/C0CC02112A
Article type: Communication
Submitted: 26 Jun 2010
Accepted: 13 Sep 2010
First published: 28 Sep 2010

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Chem. Commun., 2010,46, 8168-8170

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Synthesis, characterization and property of a mixed-valent Ag^I/Ag^II coordination polymer

D. Sun, C. Yang, H. Xu, H. Zhao, Z. Wei, N. Zhang, L. Yu, R. Huang and L. Zheng, Chem. Commun., 2010, 46, 8168 DOI: 10.1039/C0CC02112A

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Chemical Communications