Issue 43, 2010
From the journal:

Chemical Communications

“On-water” conjugate additions of anilines†

Christopher B. W. Phippen,a   James K. Beattiea  and  Christopher S. P. McErlean*a  

* Corresponding authors

a School of Chemistry, The University of Sydney, NSW, Australia
E-mail: christopher.mcerlean@sydney.edu.au
Fax: +61 2 9351 3329
Tel: +61 2 9351 3970

Abstract

The conjugate addition of anilines onto unsaturated ketones, esters and N-acylpyrroles was investigated. Based on a recently proposed explanation for the phenomenon of on-water catalysis, operationally simple and mild reaction conditions for effecting these addition reactions have been developed. The success of these additions provides further support for the acid-catalysed nature of on-water chemistry.

Graphical abstract: “On-water” conjugate additions of anilines

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Article information

DOI
https://doi.org/10.1039/C0CC02502J
Article type
Communication
Submitted
12 Jul 2010
Accepted
08 Sep 2010
First published
28 Sep 2010

Chem. Commun., 2010,46, 8234-8236

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“On-water” conjugate additions of anilines

C. B. W. Phippen, J. K. Beattie and C. S. P. McErlean, Chem. Commun., 2010, 46, 8234 DOI: 10.1039/C0CC02502J

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