Issue 41, 2010
From the journal:

Chemical Communications

Reactions of dizincocene with sterically demanding bis(iminodi(phenyl)phosphorano)methanes†

Stephan Schulz,*a   Sebastian Gondzik,a   Daniella Schuchmann,a   Ulrich Westphal,a   Lukasz Dobrzycki,a   Roland Boesea  and  Sjoerd Harderb  

* Corresponding authors

a University of Duisburg-Essen, Universitätsstr., 5-7, S07 S03 C30, 45117 Essen, Germany
E-mail: stephan.schulz@uni-due.de
Fax: +201 1833830
Tel: +201 1834635

b University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands
E-mail: s.harder@rug.nl
Tel: +31 50 3634322

Abstract

Reactions of Cp*2Zn2 with sterically demanding bis(iminodi(phenyl)phosphorano)methanes LH (LH = CH2(Ph2P[double bond, length as m-dash]NR)2 (R = Ph L1H, SiMe3L2H, 2,6-i-Pr2C6H3 (Dipp) L3H) at ambient temperature occurred with elimination of Cp*H and subsequent formation of the homoleptic complex L12Zn21 and the heteroleptic complexes LZnZnCp* (L = L22, L33, L14). 3 is the first structurally characterized heteroleptic organozinc complex with the zinc atoms in the formal oxidation state +1.

Graphical abstract: Reactions of dizincocene with sterically demanding bis(iminodi(phenyl)phosphorano)methanes

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Article information

DOI
https://doi.org/10.1039/C0CC02859B
Article type
Communication
Submitted
28 Jul 2010
Accepted
26 Aug 2010
First published
08 Sep 2010

Chem. Commun., 2010,46, 7757-7759

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Reactions of dizincocene with sterically demanding bis(iminodi(phenyl)phosphorano)methanes

S. Schulz, S. Gondzik, D. Schuchmann, U. Westphal, L. Dobrzycki, R. Boese and S. Harder, Chem. Commun., 2010, 46, 7757 DOI: 10.1039/C0CC02859B

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