Issue 45, 2010
From the journal:

Chemical Communications

Deep cavitand receptors with pH-independent water solubility†

Agustí Lledóa  and  Julius Rebek Jr.*a  

* Corresponding authors

a The Skaggs Institute for Chemical Biology and Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA
E-mail: jrebek@scripps.edu

Abstract

Pendant oligoethyleneglycol groups confer water solubility to a cavitand over a wide pH range. The kinetic stability of the host–guest complexes reveals an effective stabilization through hydrogen bonding even in the highly competitive aqueous environment.

Graphical abstract: Deep cavitand receptors with pH-independent water solubility

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Article information

DOI
https://doi.org/10.1039/C0CC03388J
Article type
Communication
Submitted
20 Aug 2010
Accepted
22 Sep 2010
First published
12 Oct 2010

Chem. Commun., 2010,46, 8630-8632

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Deep cavitand receptors with pH-independent water solubility

A. Lledó and J. Rebek Jr., Chem. Commun., 2010, 46, 8630 DOI: 10.1039/C0CC03388J

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