Issue 47, 2010
From the journal:

Chemical Communications

Tandem isomerisation–metathesiscatalytic processes of linear olefins in ionic liquid biphasic system†

Crestina S. Consorti,*a   Guilherme L. P. Aydosa  and  Jairton Dupont*a  

* Corresponding authors

a Laboratory of Molecular Catalysis, Institute of Chemistry - UFRGS, Avenida Bento Gonçalves, 9500 P.O. Box 15003, Porto Alegre, RS, Brazil
E-mail: jairton.dupont@ufrgs.br
Fax: +55 51 33087304
Tel: +55 51 3308 6321

Abstract

trans-3-Hexene is converted to heavier linear olefins by a tandem Ru-catalysed biphasic isomerisation/metathesis sequence. The difference in olefin metathesis and isomerisation rates is modulated by keeping the ionophilic metathesis catalyst in an ionic phase whilst the isomerisation catalyst is in another organic non-polar phase.

Graphical abstract: Tandem isomerisation–metathesis catalytic processes of linear olefins in ionic liquid biphasic system

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Article information

DOI
https://doi.org/10.1039/C0CC03891A
Article type
Communication
Submitted
15 Sep 2010
Accepted
11 Oct 2010
First published
25 Oct 2010

Chem. Commun., 2010,46, 9058-9060

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Tandem isomerisation–metathesis catalytic processes of linear olefins in ionic liquid biphasic system

C. S. Consorti, G. L. P. Aydos and J. Dupont, Chem. Commun., 2010, 46, 9058 DOI: 10.1039/C0CC03891A

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