Issue 12, 2010
From the journal:

CrystEngComm

A one-dimensional homochiral Mo(iv)-Cu(ii) coordination polymer: spontaneous resolution and photoresponsive properties†

Wen Zhang,ab   Hao-Ling Sunc  and  Osamu Sato*b  

* Corresponding authors

a Ordered Matter Science Research Center, Southeast University, Nanjing, Jiangsu, China

b Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka, Japan
E-mail: sato@cm.kyushu-u.ac.jp
Fax: (+81)-92-583-7787
Tel: (+81)-92-583-7787

c Department of Chemistry, Beijing Normal University, Beijing, China

Abstract

A one-dimensional homochiral MoIVCuII compound, [Cu(tren)][Cu(33)][Mo(CN)8]·4H2O (1, tren = tris(2-aminoethyl)amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P21. It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.

Graphical abstract: A one-dimensional homochiral Mo(iv)-Cu(ii) coordination polymer: spontaneous resolution and photoresponsive properties

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Article information

DOI
https://doi.org/10.1039/C0CE00178C
Article type
Communication
Submitted
07 May 2010
Accepted
17 Aug 2010
First published
07 Sep 2010

CrystEngComm, 2010,12, 4045-4047

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A one-dimensional homochiral Mo(IV)-Cu(II) coordination polymer: spontaneous resolution and photoresponsive properties

W. Zhang, H. Sun and O. Sato, CrystEngComm, 2010, 12, 4045 DOI: 10.1039/C0CE00178C

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