Issue 1, 2011
From the journal:

Chemical Communications

α-Aroyloxyaldehydes: scope and limitations as alternatives to α-haloaldehydes for NHC-catalysed redox transformations†‡

Kenneth B. Linga  and  Andrew D. Smith*a  

* Corresponding authors

a EaStCHEM, School of Chemistry, University of St Andrews, North Haugh, St Andrews, UK
E-mail: ads10@st.andrews.ac.uk

Abstract

α-Aroyloxyaldehydes are readily prepared bench stable synthetic intermediates. Their ability to act as α-haloaldehyde surrogates for NHC-promoted redox esterifications and in [4+2] cycloadditions is described.

Graphical abstract: α-Aroyloxyaldehydes: scope and limitations as alternatives to α-haloaldehydes for NHC-catalysed redox transformations

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Article information

DOI
https://doi.org/10.1039/C0CC02456B
Article type
Communication
Submitted
09 Jul 2010
Accepted
06 Aug 2010
First published
23 Aug 2010

Chem. Commun., 2011,47, 373-375

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α-Aroyloxyaldehydes: scope and limitations as alternatives to α-haloaldehydes for NHC-catalysed redox transformations

K. B. Ling and A. D. Smith, Chem. Commun., 2011, 47, 373 DOI: 10.1039/C0CC02456B

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