Issue 21, 2011
From the journal:

Chemical Communications

Manganese(iii) acetate-mediated radical reaction of [60]fullerene with phosphonate esters affording unprecedented separable singly-bonded [60]fullerene dimers†

Guan-Wu Wang,*a   Cong-Zhou Wang,a   San-E Zhua  and  Yasujiro Murata*b  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry, Joint Laboratory of Green Synthetic Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China
E-mail: gwang@ustc.edu.cn
Fax: (+86) 551 3607864
Tel: (+86) 551 3607864

b Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan
E-mail: yasujiro@scl.kyoto-u.ac.jp

Abstract

Radical reaction of [60]fullerene with phosphonate esters mediated by manganese(III) acetate in chlorobenzene afforded singly-bonded fullerene dimers, of which the individual meso and racemic isomers could be unexpectedly separated out for the first time.

Graphical abstract: Manganese(iii) acetate-mediated radical reaction of [60]fullerene with phosphonate esters affording unprecedented separable singly-bonded [60]fullerene dimers

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Article information

DOI
https://doi.org/10.1039/C1CC10820D
Article type
Communication
Submitted
12 Feb 2011
Accepted
25 Mar 2011
First published
21 Apr 2011

Chem. Commun., 2011,47, 6111-6113

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Manganese(III) acetate-mediated radical reaction of [60]fullerene with phosphonate esters affording unprecedented separable singly-bonded [60]fullerene dimers

G. Wang, C. Wang, S. Zhu and Y. Murata, Chem. Commun., 2011, 47, 6111 DOI: 10.1039/C1CC10820D

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