Issue 22, 2011
From the journal:

Chemical Communications

Synthesis of thiol-clickable and block copolypeptide brushes vianickel-mediated surface initiated polymerization of α-amino acid N-carboxyanhydrides (NCAs)†‡

Bradley J. Sparks,a   Jacob G. Ray,a   Daniel A. Savin,a   Christopher M. Staffordb  and  Derek L. Patton*a  

* Corresponding authors

a School of Polymers and High Performance Materials, The University of Southern Mississippi, 118 College Drive # 10076, Hattiesburg, USA
E-mail: derek.patton@usm.edu
Tel: +1 601-266-4229

b Polymers Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA

Abstract

We describe the synthesis of homo-, block, and clickable copolypeptide brushes from low surface area substrates using nickel-mediated surface-initiated polymerization of α-aminoN-carboxyanhydrides.

Graphical abstract: Synthesis of thiol-clickable and block copolypeptide brushes vianickel-mediated surface initiated polymerization of α-amino acid N-carboxyanhydrides (NCAs)

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Article information

DOI
https://doi.org/10.1039/C1CC11534K
Article type
Communication
Submitted
17 Mar 2011
Accepted
31 Mar 2011
First published
19 Apr 2011

Chem. Commun., 2011,47, 6245-6247

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Synthesis of thiol-clickable and block copolypeptide brushes vianickel-mediated surface initiated polymerization of α-amino acid N-carboxyanhydrides (NCAs)

B. J. Sparks, J. G. Ray, D. A. Savin, C. M. Stafford and D. L. Patton, Chem. Commun., 2011, 47, 6245 DOI: 10.1039/C1CC11534K

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