Issue 26, 2011
From the journal:

Chemical Communications

Activation of olefins with low-valent gallium compounds under ambient conditions†

Christine A. Caputo,a   Zhongliang Zhu,a   Zachary D. Brown,a   James C. Fettingera  and  Philip P. Power*a  

* Corresponding authors

a Department of Chemistry, The University of California, 1 Shields Ave., Davis, CA, USA
E-mail: pppower@ucdavis.edu
Fax: 530-732-8995
Tel: 530-752-8900

Abstract

The reactions of Ar′GaGaAr′ (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) with alkenes revealed the addition of two olefins per Ar′GaGaAr′ under ambient conditions for ethylene, propene, 1-hexene and styrene but no reactions with more hindered or cyclic olefins.

Graphical abstract: Activation of olefins with low-valent gallium compounds under ambient conditions

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Article information

DOI
https://doi.org/10.1039/C1CC11676B
Article type
Communication
Submitted
23 Mar 2011
Accepted
05 May 2011
First published
31 May 2011

Chem. Commun., 2011,47, 7506-7508

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Activation of olefins with low-valent gallium compounds under ambient conditions

C. A. Caputo, Z. Zhu, Z. D. Brown, J. C. Fettinger and P. P. Power, Chem. Commun., 2011, 47, 7506 DOI: 10.1039/C1CC11676B

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