Solvent-free selective hydrogenation of chloronitrobenzene to chloroaniline over a robust Pt/Fe3O4 catalyst

Chao Lian; Hongquan Liu; Chao Xiao; Wen Yang; Kai Zhang; Yan Liu; Yuan Wang

doi:10.1039/C2CC16620H

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Solvent-free selective hydrogenation of chloronitrobenzene to chloroaniline over a robust Pt/Fe₃O₄ catalyst†

Chao Lian,^a Hongquan Liu,^a Chao Xiao,^a Wen Yang,^a Kai Zhang,^a Yan Liu^a and Yuan Wang*^a

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* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
E-mail: wangy@pku.edu.cn
Fax: +86 10 6276 5769

Abstract

In the absence of solvent, highly selective hydrogenation of o-chloronitrobenzene and m-chloronitrobenzene, with selectivity to the corresponding chloroanilines of ≥99.4% and complete conversion of the substrates, was realized over a robust Pt/Fe₃O₄ catalyst which was prepared by adsorbing Pt nanoclusters on a Fe₃O₄ support.

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Article information

DOI: https://doi.org/10.1039/C2CC16620H
Article type: Communication
Submitted: 25 Oct 2011
Accepted: 30 Jan 2012
First published: 30 Jan 2012

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Chem. Commun., 2012,48, 3124-3126

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Solvent-free selective hydrogenation of chloronitrobenzene to chloroaniline over a robust Pt/Fe₃O₄ catalyst

C. Lian, H. Liu, C. Xiao, W. Yang, K. Zhang, Y. Liu and Y. Wang, Chem. Commun., 2012, 48, 3124 DOI: 10.1039/C2CC16620H

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