A π–π 3D network of tetranuclear μ2/μ3-carbonato Dy(III) bis-pyrazolylpyridine clusters showing single molecule magnetism features

Ian A. Gass; Boujemaa Moubaraki; Stuart K. Langley; Stuart R. Batten; Keith S. Murray

doi:10.1039/C2CC16946K

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A π–π 3D network of tetranuclear μ₂/μ₃-carbonato Dy(iii) bis-pyrazolylpyridine clusters showing single molecule magnetism features†

Ian A. Gass,^a Boujemaa Moubaraki,^a Stuart K. Langley,^a Stuart R. Batten^a and Keith S. Murray*^a

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* Corresponding authors

^a School of Chemistry, Monash University, Clayton, Victoria 3800, Australia
E-mail: keith.murray@monash.edu

Abstract

2,6-Di(pyrazole-3-yl)pyridine, 3-bpp, forms a porous (4⁹·6⁶) π–π mediated 3D network of trigonal pyramidal [Dy^III₄] carbonato-bridged complexes, with hexagonal channels comprising 54% of the unit cell volume, the material displaying slow magnetisation reversal.

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Article information

DOI: https://doi.org/10.1039/C2CC16946K
Article type: Communication
Submitted: 09 Nov 2011
Accepted: 06 Dec 2011
First published: 12 Dec 2011

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Chem. Commun., 2012,48, 2089-2091

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A π–π 3D network of tetranuclear μ₂/μ₃-carbonato Dy(III) bis-pyrazolylpyridine clusters showing single molecule magnetism features

I. A. Gass, B. Moubaraki, S. K. Langley, S. R. Batten and K. S. Murray, Chem. Commun., 2012, 48, 2089 DOI: 10.1039/C2CC16946K

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