Issue 21, 2012

A lab-on-a-molecule for anions in aqueous solution: using Kolbe electrolysis and radical methylation at iridium for sensing

Abstract

Iridium complex [(pq)2IrCl]2 (1) is established as a quantitatively operating lab-on-a-molecule in aqueous media at physiological pH. Acting as a chemodosimeter, 1 uses two channels, PL and ECL, for the detection of cyanide and acetate, with the former undergoing nucleophilic attack and the latter Kolbe electrolysis and radical–metal combination.

Graphical abstract: A lab-on-a-molecule for anions in aqueous solution: using Kolbe electrolysis and radical methylation at iridium for sensing

Supplementary files

Article information

Article type
Communication
Submitted
09 Dec 2011
Accepted
19 Jan 2012
First published
03 Feb 2012

Chem. Commun., 2012,48, 2707-2709

A lab-on-a-molecule for anions in aqueous solution: using Kolbe electrolysis and radical methylation at iridium for sensing

M. Schmittel and S. Qinghai, Chem. Commun., 2012, 48, 2707 DOI: 10.1039/C2CC17731E

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