Issue 53, 2012

Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality

Abstract

We observed the emergence and inversion of chiroptical handedness in three chiroptically silent dialkylpolysilanes during aggregation in limonenemethanol–THF tersolvents.

Graphical abstract: Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality

  • This article is part of the themed collection: Chirality

Supplementary files

Article information

Article type
Communication
Submitted
15 Dec 2011
Accepted
09 Feb 2012
First published
10 Feb 2012

Chem. Commun., 2012,48, 6636-6638

Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality

Y. Nakano, F. Ichiyanagi, M. Naito, Y. Yang and M. Fujiki, Chem. Commun., 2012, 48, 6636 DOI: 10.1039/C2CC17845A

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