CO oxidation at nickel centres by N2O or O2 to yield a novel hexanuclear carbonate

Bettina Horn; Christian Limberg; Christian Herwig; Michael Feist; Stefan Mebs

doi:10.1039/C2CC33846G

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CO oxidation at nickel centres by N₂O or O₂ to yield a novel hexanuclear carbonate†

Bettina Horn,^a Christian Limberg,*^a Christian Herwig,^a Michael Feist^a and Stefan Mebs^a

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* Corresponding authors

^a Humboldt-Universität zu Berlin, Institut für Chemie, Brook-Taylor-Str. 2, 12489 Berlin, Germany
E-mail: christian.limberg@chemie.hu-berlin.de
Fax: +49 30-2093-6966
Tel: +49 30-2093-7370

Abstract

Reaction of a nickel(0) carbonyl complex, K₂[L^tBuNiCO]₂, with N₂O generates a cyclic carbonate compound composed of six [Ni^II(CO₃)K]⁺ units. The same product can also be obtained using O₂ as the oxidant in a solid-state/gas reaction. These conversions represent unique examples of a nickel-bound CO oxidation by N₂O and O₂, respectively.

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Article information

DOI: https://doi.org/10.1039/C2CC33846G
Article type: Communication
Submitted: 29 May 2012
Accepted: 27 Jun 2012
First published: 12 Jul 2012

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Chem. Commun., 2012,48, 8243-8245

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CO oxidation at nickel centres by N₂O or O₂ to yield a novel hexanuclear carbonate

B. Horn, C. Limberg, C. Herwig, M. Feist and S. Mebs, Chem. Commun., 2012, 48, 8243 DOI: 10.1039/C2CC33846G

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