Issue 85, 2012

Chiral recognition in metal–organic frameworks studied by solid-state NMRspectroscopy using chiral solvating agents

Abstract

Recently, we have described the synthesis of chiral metal–organic frameworks iPr-ChirUMCM-1 and Bn-ChirUMCM-1 and their use in enantioselective separation. Here, we demonstrate for the first time the use of a chiral solvating agent (1-phenyl-2,2,2-trifluoroethanol, TFPE) for chiral recognition in iPr-ChirUMCM-1 and Bn-ChirUMCM-1 by means of solid-state13C NMR spectroscopy.

Graphical abstract: Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

  • This article is part of the themed collection: Chirality

Supplementary files

Article information

Article type
Communication
Submitted
25 Jul 2012
Accepted
15 Aug 2012
First published
16 Aug 2012

Chem. Commun., 2012,48, 10484-10486

Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

H. C. Hoffmann, S. Paasch, P. Müller, I. Senkovska, M. Padmanaban, F. Glorius, S. Kaskel and E. Brunner, Chem. Commun., 2012, 48, 10484 DOI: 10.1039/C2CC35366K

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