Issue 45, 2012
From the journal:

Dalton Transactions

Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66)†

Maw Lin Foo,ab   Satoshi Horike,cd   Tomohiro Fukushima,c   Yuh Hijikata,c   Yoshiki Kubota,e   Masaki Takataf  and  Susumu Kitagawa*abc  

* Corresponding authors

a Japan Science and Technology Agency, ERATO, Kitagawa Integrated Pores Project, Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815, Japan

b Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

c Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: kitagawa@sbchem.kyoto-u.ac.jp
Fax: +81-75-383-2732
Tel: +81-75-383-2733

d Japan Science and Technology Agency, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

e Osaka Prefecture University, Japan

f Japan Synchrotron Radiation Research Institute/SPring-8 Sayo-gun, Hyogo 679-5198, Japan

Abstract

By adopting a ligand-based solid solution approach, the sulphonic acid functional group can be successfully incorporated into a porous coordination polymer with UiO-66 structure type. Zr6O4(OH)4(BDC-SO3H)1.1(BDC)4.9 possesses enhanced heat of adsorption for carbon dioxide and acetone compared to Zr6O4(OH)4(BDC)6.

Graphical abstract: Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66)

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Article information

DOI
https://doi.org/10.1039/C2DT31195J
Article type
Communication
Submitted
04 Jun 2012
Accepted
16 Jul 2012
First published
17 Jul 2012

Dalton Trans., 2012,41, 13791-13794

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Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66)

M. Lin Foo, S. Horike, T. Fukushima, Y. Hijikata, Y. Kubota, M. Takata and S. Kitagawa, Dalton Trans., 2012, 41, 13791 DOI: 10.1039/C2DT31195J

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