We herein report the synthesis of a bis-2-pyridylidene palladium(II) complex as an isoelectronic structure of the well-known 2,2′-bipyridine complexes. One-pot or stepwise C–Cl oxidative addition followed by base-mediated C–H palladation of the chlorobipyridine dication to palladium(0) yielded the bis-2-pyridylidene palladium(II) carbonate smoothly.
T. Yoshidomi, Y. Segawa and K. Itami, Chem. Commun., 2013, 49, 5648 DOI: 10.1039/C3CC42655F
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