Issue 91, 2013
From the journal:

Chemical Communications

Unexpected isocyanide-based cascade cycloaddition reaction with methyleneindolinone†

Jian Li,*a   Shikuan Su,a   Mengyuan Huang,a   Boyi Song,a   Chunju Lia  and  Xueshun Jia*ab  

* Corresponding authors

a Department of Chemistry, Shanghai University, Shanghai, P. R. China
E-mail: lijian@shu.edu.cn, xsjia@mail.shu.edu.cn
Fax: +86-21-66132408
Tel: +86-21-66132408

b Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 345 Lingling road, Shanghai, P. R. China

Abstract

An unprecedented cascade reaction of isocyanide and methyleneindolinone has been established, which represents a novel and different reaction mode. This present transformation involves the ring-opening of methyleneindolinone and the construction of two other new rings simultaneously in an atom-economic manner.

Graphical abstract: Unexpected isocyanide-based cascade cycloaddition reaction with methyleneindolinone

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Article information

DOI
https://doi.org/10.1039/C3CC46237D
Article type
Communication
Submitted
14 Aug 2013
Accepted
20 Sep 2013
First published
26 Sep 2013

Chem. Commun., 2013,49, 10694-10696

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Unexpected isocyanide-based cascade cycloaddition reaction with methyleneindolinone

J. Li, S. Su, M. Huang, B. Song, C. Li and X. Jia, Chem. Commun., 2013, 49, 10694 DOI: 10.1039/C3CC46237D

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