Issue 2, 2014
From the journal:

Chemical Communications

Palladium-catalyzed stereospecific cross-coupling of enantioenriched allylic alcohols with boronic acids†

Hai-Bian Wu,a   Xian-Tao Maa  and  Shi-Kai Tian*ab  

* Corresponding authors

a Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
E-mail: tiansk@ustc.edu.cn
Fax: +86 551-6360-1592
Tel: +86 551-6360-0871

b Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

In the presence of 2.5 mol% Pd2(dba)3–TMEDA (1 : 4), a range of enantioenriched allylic alcohols smoothly coupled with boronic acids in a highly regioselective fashion with inversion of configuration to afford structurally diverse alkenes in good yields with perfect retention of ee.

Graphical abstract: Palladium-catalyzed stereospecific cross-coupling of enantioenriched allylic alcohols with boronic acids

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC45772A
Article type
Communication
Submitted
29 Jul 2013
Accepted
30 Oct 2013
First published
30 Oct 2013

Chem. Commun., 2014,50, 219-221

Permissions

Request permissions

Palladium-catalyzed stereospecific cross-coupling of enantioenriched allylic alcohols with boronic acids

H. Wu, X. Ma and S. Tian, Chem. Commun., 2014, 50, 219 DOI: 10.1039/C3CC45772A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements