Single crystals of (NH4)14[Hf9O8(OH)6(SO4)14]·nH2O (1) were obtained by heating a sealed aqueous solution of HfOCl2·8H2O, (NH4)2SO4 and H2SO4 at 80 °C for 10 days. The discrete [Hf9O8(OH)6(SO4)14]14− anionic clusters have no inter-cluster connectivity. This rare nonameric architecture has only been observed previously in two Bi3+ oxo clusters.
A. Kalaji and L. Soderholm, Chem. Commun., 2014, 50, 997 DOI: 10.1039/C3CC48167K
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