The first single chain magnet (SCM) based on orbitally degenerate hexacyanoosmate(III) was prepared. The high values of energy barriers for the [Mn(acacen)Os(CN)6]2− complex of 81 and 48.4 K are the result of interplay of three axes anisotropic coupling of [Os(CN)6]3− with zero field splitted Mn3+.
E. V. Peresypkina, A. M. Majcher, M. Rams and K. E. Vostrikova, Chem. Commun., 2014, 50, 7150 DOI: 10.1039/C3CC48972H
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